Abstract
Numerous supramolecular macrocycles have been utilized for developing catalysts by exploiting their spe-cific molecular recognition and ability to form inclusion complexes through noncovalent interactions.The cyclic structure and modified functional groups of these macrocycles can influence substrate and transi-tion state stability,as well as reaction selectivity.The inner cavities of these macrocycles are particularly beneficial,as they enable substrates to adopt preorganized arrangements and serve as versatile platforms for highly efficient supramolecular catalytic systems.This minireview provides an overview of recent ad-vancements in supramolecular catalysis using various macrocycles,such as crown ethers,cyclodextrins,calixarenes,pillararenes,cucurbiturils,and other novel macrocycles.
基金项目
Start-up Grant of Henan University of Technology(0004/31401509)
Distinguished University Professor grant(Nanyang Technological University)()
AcRF Tier 1 grants from the Ministry of Education of Singapore(RG107/19)
AcRF Tier 1 grants from the Ministry of Education of Singapore(RG11/20)
AcRF Tier 1 grants from the Ministry of Education of Singapore(RT14/20)
Agency for Science,Technology and Re-search(A*STAR)under its MTC Individual Research Grants(M21K2c0114)
NETL
NSTL
万方数据