首页|Recent applications of macrocycles in supramolecular catalysis

Recent applications of macrocycles in supramolecular catalysis

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Numerous supramolecular macrocycles have been utilized for developing catalysts by exploiting their spe-cific molecular recognition and ability to form inclusion complexes through noncovalent interactions.The cyclic structure and modified functional groups of these macrocycles can influence substrate and transi-tion state stability,as well as reaction selectivity.The inner cavities of these macrocycles are particularly beneficial,as they enable substrates to adopt preorganized arrangements and serve as versatile platforms for highly efficient supramolecular catalytic systems.This minireview provides an overview of recent ad-vancements in supramolecular catalysis using various macrocycles,such as crown ethers,cyclodextrins,calixarenes,pillararenes,cucurbiturils,and other novel macrocycles.

Supramolecular catalysisMacrocycleHost-guest interactionsConfinementSelectivity

Conghui Wang、Lei Xu、Zhenhua Jia、Teck-Peng Loh

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College of Advanced Interdisciplinary Science and Technology,Henan University of Technology,Zhengzhou 450001,China

Division of Chemistry and Biological Chemistry,School of Chemistry Chemical Engineering,and Biotechnology,Nanyang Technological University,Singapore 637371,Singapore

Institute of Advanced Synthesis,School of Chemistry and Molecular Engineering Nanjing Tech University,Nanjing 211816,China

Start-up Grant of Henan University of TechnologyDistinguished University Professor grant(Nanyang Technological University)AcRF Tier 1 grants from the Ministry of Education of SingaporeAcRF Tier 1 grants from the Ministry of Education of SingaporeAcRF Tier 1 grants from the Ministry of Education of SingaporeAgency for Science,Technology and Re-search(A*STAR)under its MTC Individual Research Grants

0004/31401509RG107/19RG11/20RT14/20M21K2c0114

2024

10.1016/j.cclet.2023.109075

中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCD
影响因子：0.771
ISSN：1001-8417
年,卷(期)：2024.35(4)
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