Enabling superior electrochemical performance of NCA cathode in Li5.5PS4.5Cl1.5-based solid-state batteries with a dual-electrolyte layer

Ziling Jiang ¹Shaoqing Chen ²Chaochao Wei ³Ziqi Zhang ⁴Zhongkai Wu ³Qiyue Luo ³Liang Ming ³Long Zhang ⁵Chuang Yu¹

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作者信息

1. School of Chemistry and Chemical Engineering,Huazhong University of Science and Technology,Wuhan 430074,China;State Key Laboratory of Advanced Electromagnetic Engineering and Technology,School of Electrical and Electronic Engineering,Huazhong University of Science and Technology,Wuhan 430074,China
2. Innovation Center for Chemical Sciences,College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China
3. School of Chemistry and Chemical Engineering,Huazhong University of Science and Technology,Wuhan 430074,China
4. State Key Laboratory of Advanced Electromagnetic Engineering and Technology,School of Electrical and Electronic Engineering,Huazhong University of Science and Technology,Wuhan 430074,China
5. College of Physics and Energy,Fujian Normal University,Fuzhou 350117 China
折叠

Abstract

LiNi0.8Co0.15Al0.05O2(NCA)is a promising cathode for sulfide-based solid-state lithium batteries(ASSLBs)profiting from its high specific capacity and voltage plateau,which yielding high energy density.How-ever,the inferior interfacial stability between the bare NCA and sulfides limits its electrochemical per-formance.Hereien,the dual-electrolyte layer is proposed to mitigate this effect and enhance the battery performances of NCA-based ASSLIBs.The Li3lnCl6 wih high conductivity and excellent electrochemcial stability act both as an ion additives to promote Li-ion diffusion across the interface in the cathode and as a buffer layer between the cathode layer and the solid electrolyte layer to avoid side reactions and improve the interface stability.The corresponding battery exhibits high discharge capacities and superior cyclabilities at both room and elevated temperatures.It exhibits discharge performance of 237.04 and 216.07 mAh/g at 0.1 and 0.5 C,respectively,when cycled at 60 ℃,and sustains 95.9％of the capacity after 100 cycles at 0.5 C.The work demonstrates a simple strategy to ensure the superior performances of NCA in sulfide-based ASSLBs.

Key words

LiNi0.8Co0.15Al0.05O2/Li5.5PS4.5Cl1.5/Double solid electrolyte layer configuration/Operating temperatures/Electrochemical performances

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基金项目

National Key Research and De-velopment Program(2021YFB2500200)

国家自然科学基金(52177214)

China Fujian Energy Devices Science and Technology In-novation Laboratory Open Fund(21C-OP202211)

出版年

2024

中国化学快报(英文版)

中国化学会

中国化学快报(英文版)

CSTPCDCSCD

影响因子：0.771

ISSN：1001-8417

参考文献量44

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