首页|Electrochemical construction of 2,5-diaryloxazoles via N-H and C(sp3)-H functionalization
Electrochemical construction of 2,5-diaryloxazoles via N-H and C(sp3)-H functionalization
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An efficient N-H and C(sp3)-H functionalization of aryl ketones with benzylamines/amino acids was developed under mild conditions by virtue of anodic oxidation.A variety of functionalized 2,5-diaryloxazoles were obtained with good to excellent yields.Moreover,some important natural products can be prepared by this method.The reaction features a broad substrate scope,scalability,metal-free and chemical oxidant-free.
ElectrochemicalMetal-freeOxazoleOxidant-free
Tong Li、Leping Pan、Yan Zhang、Jihu Su、Kai Li、Kuiliang Li、Hu Chen、Qi Sun、Zhiyong Wang
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Hefei National Center for Physical Sciences at Microscale,Key Laboratory of Precision and Intelligent Chemistry,School of Chemistry and Materials Science,University of Science and Technology of China,Hefei 230026,China
Anhui University of Science and Technology,Huainan 232001,China
CAS Key Laboratory of Microscale Magnetic Resonance,Department of Modern Physics,University of Science and Technology of China,Hefei 230026,China
国家自然科学基金国家自然科学基金Science and Technology Major Project of An-hui Province of ChinaScience and Technology Major Project of Fuyang of Anhui Province of China
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