首页|Rhodium-catalyzed Doyle-Kirmse rearrangement reactions of sulfoxoniun ylides
Rhodium-catalyzed Doyle-Kirmse rearrangement reactions of sulfoxoniun ylides
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Doyle-Kirmse rearrangement reactions have received continuous attention as an important method for constructing complex chemical structures.Herein,we disclosed an efficient rhodium-catalyzed Doyle-Kirmse rearrangement reaction,which can simultaneously construct C-C bonds and C-X(X=S/Se)bonds using sulfoxonium ylides as starting materials to obtain sulfur-or selenium-containing compounds.This strategy is characterized by the safer and greener carbene precursor,high yields and broad substrate scope,possessing a wide range of application.
Sulfoxonium ylidesRhodium(Ⅱ)-catalyzedCarbeneRearrangement reactionsOne-pot process
Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Department of Medicinal Chemistry,Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology,West China School of Pharmacy,Sichuan University,Chengdu 610041,China
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