Abstract
Doyle-Kirmse rearrangement reactions have received continuous attention as an important method for constructing complex chemical structures.Herein,we disclosed an efficient rhodium-catalyzed Doyle-Kirmse rearrangement reaction,which can simultaneously construct C-C bonds and C-X(X=S/Se)bonds using sulfoxonium ylides as starting materials to obtain sulfur-or selenium-containing compounds.This strategy is characterized by the safer and greener carbene precursor,high yields and broad substrate scope,possessing a wide range of application.
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