首页|Magnetic,dielectric and luminescence synergetic switchable effects in molecular material[Et3NCH-2Cl]2[MnBr4]
Magnetic,dielectric and luminescence synergetic switchable effects in molecular material[Et3NCH-2Cl]2[MnBr4]
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The application of multifunctional materials in various fields such as electronics and signal processors has attracted massive attention.Herein,a new organic-inorganic hybrid material[Et3NCH2CI]2[MnBr4](1)is reported,which contains two organic amines cations and one[MnBr4]tetrahedral ion.Compound 1 has a dielectric anomaly signal at 338 K,which proves its thermodynamic phase transition.The single crys-tal measurements at 200 K and 380 K show that the phase transition of compound 1 is caused by the thermal vibration of organic amine cations in the lattice.Moreover,compound 1 shows yellow-green lu-minescence under UV light irradiation.The magnetism measurements indicate that compound 1 shows switchable magnetic properties.This organic-inorganic material is a multifunctional material with di-electric,optical,and magnetic synergetic switchable effects,which expands a new direction for designing multifunctional materials.
Yan Cheng、Hua-Peng Ruan、Yan Peng、Longhe Li、Zhenqiang Xie、Lang Liu、Shiyong Zhang、Hengyun Ye、Zhao-Bo Hu
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Chaotic Matter Science Research Center,Faculty of Materials Metallurgy and Chemistry,Jiangxi University of Science and Technology,Ganzhou 341000,China
College of Materials and Chemical Engineering,Pingxiang University,Pingxiang 337055,China
Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry,Jiangxi University of Science and Technology,Ganzhou 341000,China
Key Laboratory of Jiangxi University for Functional Materials Chemistry,School of Chemistry and Chemical Engineering,Gannan Normal University,Ganzhou 341000,China
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国家自然科学基金国家自然科学基金国家自然科学基金江西省自然科学基金江西省自然科学基金江西省自然科学基金Jiangxi Provincial Key Laboratory of Functional Molecular Materi-als Chemistry