Efficient blue-light-excitable copper(Ⅰ)coordination network phosphors for high-performance white LEDs

Pingping Wang ¹Huixian Miao ¹Kechuan Sheng ¹Bin Wang ¹Fan Feng ¹Xuankun Cai ¹Wei Huang ¹Dayu Wu¹

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作者信息

1. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology,Advanced Catalysis & Green Manufacturing Collaborative Innovation Center,School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China
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Abstract

The blue-light-excitable phosphors play a crucial role in the high-performance white LEDs.Here,we re-port on two new Cu(Ⅰ)coordination network materials as yellow-emitting phosphors prepared by suit-ably expanded π-conjugated triazole ligands.Upon blue-light irradiation,these complexes exhibit effi-cient solid-state emission and enhanced photostability.Through incorporating the yellow phosphor and a commercial blue-green powder(BaSi2N2O2:Eu2+)with a blue LED chip,the phosphor-converted LED de-vices display remarkable white emission properties.The experimental results demonstrate that the Cu(I)coordination network materials function as promising blue-light excitable phosphors with great applica-tion potential for full-spectrum white LEDs.

Key words

Metal-organic framework/Coordination polymer/Photoluminescence/Phosphor material/White-light LED/Phosphor-converted LED

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基金项目

PAPD of Jiangsu Higher Education Institutions()

国家自然科学基金(92161121)

出版年

2024

中国化学快报(英文版)

中国化学会

中国化学快报(英文版)

CSTPCDCSCD

影响因子：0.771

ISSN：1001-8417

参考文献量52

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