中国化学快报(英文版)2024，Vol.35Issue(4) ：539-543.DOI:10.1016/j.cclet.2023.108542

Molar ratio induced crystal transformation from coordination complex to coordination polymers

Peng Meng Qian-Cheng Luo Aidan Brock Xiaodong Wang Mahboobeh Shahbazi Aaron Micallef John McMurtrie Dongchen Qi Yan-Zhen Zheng Jingsan Xu
中国化学快报(英文版)2024，Vol.35Issue(4) ：539-543.DOI:10.1016/j.cclet.2023.108542
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Molar ratio induced crystal transformation from coordination complex to coordination polymers

Peng Meng 1Qian-Cheng Luo 2Aidan Brock 1Xiaodong Wang 3Mahboobeh Shahbazi 1Aaron Micallef 3John McMurtrie 1Dongchen Qi 1Yan-Zhen Zheng 2Jingsan Xu1
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作者信息

  • 1. School of Chemistry and Physics & Centre for Materials Science,Queensland University of Technology,Brisbane,QLD 4000,Australia
  • 2. Frontier Institute of Science and Technology,Xi'an Jiaotong University,Xi'an 710054,China
  • 3. Central Analytical Research Facility,Institute for Future Environments,Queensland University of Technology,Brisbane,QLD 4000,Australia
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Abstract

Coordination complex of a copper cyanurate(Cu(Ⅱ)-CA)was transformed into coordination polymers upon the stimulus of extra Cu(Ⅱ)through"directed Ostwald ripening".By increasing the molar ratio of Cu(Ⅱ)to CA,we obtained two coordination polymers with selective coordination sites:Cu(Ⅱ)-κN(HCA)κN-Cu(Ⅱ)and Cu(Ⅱ)-κN(HCA)κO-Cu(Ⅱ),which display disparate magnetic interactions.

Key words

Molar ratio dependent crystal transformation/Copper cyanurate/Ostwald ripening/Molecular magnetism/One-dimensional chain

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基金项目

Australian Research Council(ARC)(DP190101607)

National Natu-ral Science Foundation of China(21971203)

出版年

2024
中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCD
影响因子：0.771
ISSN：1001-8417
参考文献量1
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