Molar ratio induced crystal transformation from coordination complex to coordination polymers

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外文摘要：Coordination complex of a copper cyanurate(Cu(Ⅱ)-CA)was transformed into coordination polymers upon the stimulus of extra Cu(Ⅱ)through"directed Ostwald ripening".By increasing the molar ratio of Cu(Ⅱ)to CA,we obtained two coordination polymers with selective coordination sites:Cu(Ⅱ)-κN(HCA)κN-Cu(Ⅱ)and Cu(Ⅱ)-κN(HCA)κO-Cu(Ⅱ),which display disparate magnetic interactions.

外文关键词：

Molar ratio dependent crystal transformationCopper cyanurateOstwald ripeningMolecular magnetismOne-dimensional chain

作者：

Peng Meng、Qian-Cheng Luo、Aidan Brock、Xiaodong Wang、Mahboobeh Shahbazi、Aaron Micallef、John McMurtrie、Dongchen Qi、Yan-Zhen Zheng、Jingsan Xu

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作者单位：

School of Chemistry and Physics & Centre for Materials Science,Queensland University of Technology,Brisbane,QLD 4000,Australia

Frontier Institute of Science and Technology,Xi'an Jiaotong University,Xi'an 710054,China

Central Analytical Research Facility,Institute for Future Environments,Queensland University of Technology,Brisbane,QLD 4000,Australia

基金：

Australian Research Council(ARC)National Natu-ral Science Foundation of China

项目编号：

DP19010160721971203

出版年：

2024

DOI：

10.1016/j.cclet.2023.108542

中国化学快报(英文版)

中国化学会

中国化学快报(英文版)

CSTPCD

影响因子：0.771

ISSN：1001-8417

年,卷(期)：2024.35(4)

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