A strained π-extended[10]cycloparaphenylene carbon nanoring
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Herein,we report the facile synthesis of a highly strained hexabenzocoronene-containing carbon nanor-ing,cyclo[4]-paraphenylene[2]-2,11-hexabenzocoronenylene([4,2]CPHBC),as the segment of a[10,10]single-walled carbon nanotube([10,10]SWNT).[4,2]CPHBC was synthesized based on the platinum-mediated assembly of diborylbiphenyl and diborylhexabenzocoronene,forming a tetranuclear platinum complex,followed by reductive elimination.This nanoring molecule was confirmed by NMR and HR-MS,and its photophysical properties were studied using steady-state and time-resolved spectroscopies.Moreover,the selective supramolecular host-guest interaction between[4,2]CPHBC and C60 was also in-vestigated.
Kang Wei、Jiayu Li、Wen Zhang、Bing Yuan、Ming-De Li、Pingwu Du
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Key Laboratory of Precision and Intelligent Chemistry,Anhui Laboratory of Advanced Photon Science and Technology,Department of Materials Science and Engineering,University of Science and Technology of China,Hefei 230026,China
Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province,Shantou University,Shantou 515063,China