中国化学快报(英文版)2024,Vol.35Issue(5) :254-258.DOI:10.1016/j.cclet.2023.109339

A simple photochemical method for surface fluorination using perfluoroketones

Zhiwei Zhong Yanbin Huang Wantai Yang
中国化学快报(英文版)2024,Vol.35Issue(5) :254-258.DOI:10.1016/j.cclet.2023.109339

A simple photochemical method for surface fluorination using perfluoroketones

Zhiwei Zhong 1Yanbin Huang 1Wantai Yang1
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作者信息

  • 1. Department of Chemical Engineering,Tsinghua University,Beijing 100084,China
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Abstract

Surface fluorination of conventional polymers can give them desirable surface properties similar to the expensive and difficult-to-process fluoropolymers.However,traditional surface fluorination tech-niques often require toxic reagents and special equipment.Here,we report a simple and effective poly-mer surface fluorination method by using safe and inexpensive perfluoro-2-methyl-3-pentanone(PFMP,C2F5C(=O)CF(CF3)2)and UV irradiation.This method is applicable to various polymer materials,and gen-erates nanometer-thick fluorinated layer on the outermost surface,significantly changing their surface properties without changing the surface morphology.

Key words

Surface fluorination/Perfluoroketone/UV irradiation/Photochemistry/Surface free energy

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基金项目

internal fund from Tsinghua University()

出版年

2024
中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCDCSCD
影响因子:0.771
ISSN:1001-8417
参考文献量46
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