Abstract
An amphiphilic derivative with a large Stokes shift by introducing flexible hydrophilic long chains into a rigid ethylene-pyrene compound have been successfully synthesized.The alkylated compound exhibited a notable change in charge distribution,facilitating cation-π interactions.Through the process of am-phiphilic self-assembly,the formation of highly ordered aggregates enabled effective photo-dimerization under 449 nm LED irradiation.Notably,this photo-responsive technology not only exhibited advanced multi-color emission effects,including white light emission but also exhibited environmentally friendly behavior in the aqueous phase.
基金项目
National Natural Science Foundation of China(21602124)
Fluorine Silicone Materials Collaborative Fund of Shandong Provincial Natural Science Foundation(ZR2021LFG007)
Key R&D Program of Shandong Province(2019JZZY020229)
Young Scholars Program of Shandong University(2018WLJH40)