Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO2 reduction

Xueyang Zhao ¹Bangwei Deng ²Hongtao Xie ²Yizhao Li ²Qingqing Ye ³Fan Dong¹

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作者信息

1. Yangtze Delta Region Institute(Huzhou),University of Electronic Science and Technology of China,Huzhou 313001,China;Institute of Fundamental and Frontier Sciences,University of Electronic Science and Technology of China,Chengdu 611731,China
2. Yangtze Delta Region Institute(Huzhou),University of Electronic Science and Technology of China,Huzhou 313001,China
3. Suzhou Industrial Technology Research Institute of Zhejiang University,Zhejiang University,Suzhou 215159,China
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Abstract

Diatomic-site catalysts(DASCs)have emerged as a kind of promising heterogeneous candidate catalysts for electrochemical CO2 reduction(ECR),which is considered to retain the advantage of single-atom cat-alysts(SACs)but also introduce opportunities to exceed the limit of single-atom catalysts.In the past few years,tremendous progress has been achieved in this field.Herein,the recent progress in ECR on DASCs has been summarized.It will start with the classification of DASCs.Then the challenges in the precise fabrication and characterization of DASCs have been emphasized.By introducing the advanced ECR performance on DASCs,superior to that on SACs,the synergistic effects of the dual metal atoms are highlighted,as this origin of the advanced ECR performance on DASCs is comprehensively summa-rized.Finally,the major challenges and perspectives of DASCs have been proposed to shed light on the development of DASCs for ECR application.

Key words

Diatomic-site metal catalyst/Electrochemical CO2 reduction/Classification/CO2 activation/Synergistic effects

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基金项目

by"Pioneer"and"Leading Goose"R&D Program of Zhejiang(2023C03017)

National Natural Science Foundation of China(22225606)

National Natural Science Foundation of China(22261142663)

National Natural Science Foundation of China(22176029)

China Postdoctoral Science Foundation(2023M730491)

Natural Science Foundation of Huzhou City(2022YZ22)

出版年

2024

中国化学快报(英文版)

中国化学会

中国化学快报(英文版)

CSTPCDCSCD

影响因子：0.771

ISSN：1001-8417

参考文献量106

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