中国化学快报(英文版)2024,Vol.35Issue(7) :178-182.DOI:10.1016/j.cclet.2023.109172

Recovery of cathode copper and ternary precursors from CuS slag derived by waste lithium-ion batteries:Process analysis and evaluation

Yun Wei Lei Zhou Wenbin Hu Liming Yang Guang Yang Chaoqiang Wang Hui Shi Fei Han Yufa Feng Xuan Ding Penghui Shao Xubiao Luo
中国化学快报(英文版)2024,Vol.35Issue(7) :178-182.DOI:10.1016/j.cclet.2023.109172

Recovery of cathode copper and ternary precursors from CuS slag derived by waste lithium-ion batteries:Process analysis and evaluation

Yun Wei 1Lei Zhou 1Wenbin Hu 2Liming Yang 1Guang Yang 3Chaoqiang Wang 4Hui Shi 1Fei Han 1Yufa Feng 1Xuan Ding 1Penghui Shao 1Xubiao Luo5
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作者信息

  • 1. National-Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization,Nanchang Hangkong University,Nanchang 330063,China
  • 2. CAS Key Laboratory of Green Process and Engineering,National Engineering Research Center of Green Recycling for Strategic Metal Resources,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,China
  • 3. Biomass Molecular Engineering Center and Anhui Provincial Key Laboratory of Microbial Pest Control,Anhui Agricultural University,Hefei 230036,China
  • 4. Jiangxi Ganfeng Recycling Technology Co.LTD.,Xinyu 338004,China
  • 5. National-Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization,Nanchang Hangkong University,Nanchang 330063,China;School of Life Science,Jinggangshan University,Ji'an 343009,China
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Abstract

The efficient and environmentally friendly recycling technology of waste residue that including abundant heavy metal produced during the recovery of lithium batteries has become a research hotspot.Herein,a novelty process of acid leaching-selective electrodeposition-deep impurity removal-regeneration was pro-posed to recovery of the CuS slag,which has been efficient transferred to high purity cathode copper and commercially available ternary precursors.Copper cathode with a purity of 99.67% was prepared under electrochemical reaction conditions at-0.55 V for 2h.A novel impurity remover-Mn powder,which was used to remove the residual impurities and as a feedstock for the ternary precursor.Finally,NCM523 was regenerated by co-precipitation.The process is superior to the traditional process in economy,energy consumption,CO2 emissions,product purity and process duration.This study provides a new approach for solid waste recovery and precious metal enrichment.

Key words

CuS slag/Electrodeposition/Cathode copper/Ternary precursor/Solid waste recovery

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基金项目

Key Project of Research and Development Plan of Jiangxi Province(20223BBG74006)

Key Project of Research and Development Plan of Jiangxi Province(20201BBE51007)

National Science Foundation of China(52060018)

National Science Fund for Distinguished Young Scholars(52125002)

出版年

2024
中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCD
影响因子:0.771
ISSN:1001-8417
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