首页|Acylfluorination of enynes via phosphine and silver catalysis
Acylfluorination of enynes via phosphine and silver catalysis
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This work describes intermolecular acylfluorination of gem-difluoroenynes using acyl fluorides as both acyl source and fluorine source.Trifluoromethyl-substituted allenones or furans could be selectively achieved via phosphine and silver catalysis.These approaches exhibit high regioselectivity,atom econ-omy and broad functionality tolerance.
Yu Mao、Yilin Liu、Xiaochen Wang、Shengyang Ni、Yi Pan、Yi Wang
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State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China
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