中国化学快报(英文版)2024,Vol.35Issue(8) :260-264.DOI:10.1016/j.cclet.2023.109443

Acylfluorination of enynes via phosphine and silver catalysis

Yu Mao Yilin Liu Xiaochen Wang Shengyang Ni Yi Pan Yi Wang
中国化学快报(英文版)2024,Vol.35Issue(8) :260-264.DOI:10.1016/j.cclet.2023.109443

Acylfluorination of enynes via phosphine and silver catalysis

Yu Mao 1Yilin Liu 1Xiaochen Wang 1Shengyang Ni 1Yi Pan 1Yi Wang1
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作者信息

  • 1. State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China
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Abstract

This work describes intermolecular acylfluorination of gem-difluoroenynes using acyl fluorides as both acyl source and fluorine source.Trifluoromethyl-substituted allenones or furans could be selectively achieved via phosphine and silver catalysis.These approaches exhibit high regioselectivity,atom econ-omy and broad functionality tolerance.

Key words

Phosphine catalysis/Silver catalysis/Difunctionalization/Allenone/Furan/Trifluoromethyl

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出版年

2024
中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

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影响因子:0.771
ISSN:1001-8417
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