中国化学快报(英文版)2024,Vol.35Issue(8) :362-366.DOI:10.1016/j.cclet.2023.109301

Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor

Yuchen Wang Yaoyu Liu Xiongfei Huang Guanjie He Kai Yan
中国化学快报(英文版)2024,Vol.35Issue(8) :362-366.DOI:10.1016/j.cclet.2023.109301

Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor

Yuchen Wang 1Yaoyu Liu 2Xiongfei Huang 2Guanjie He 3Kai Yan2
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作者信息

  • 1. Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology,School of Environmental Science and Engineering,Sun Yat-sen University,Guangzhou 510275,China;Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education),Nankai University,Tianjin 300071,China
  • 2. Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology,School of Environmental Science and Engineering,Sun Yat-sen University,Guangzhou,510275,China
  • 3. Electrochemical Innovation Lab,Department of Chemical Engineering,University College London,London,WC1E 7JE,United Kingdom
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Abstract

Metal-nanocluster materials have gradually become a promising electrode candidate for supercapaci-tor application.The high-efficient and rational architecture of these metal-nanocluster electrode mate-rials with satisfied supercapacitive performance are full of challenges.Herein,Fe-nanocluster anchored porous carbon(FAPC)nanosheets were constructed through a facile and low-cost impregnation-activation strategy.Various characterization methods documented that FAPC nanosheets possessed a mesopore-dominated structure with large surface area and abundant Fe-N4 active sites,which are crucial for su-percapacitive energy storage.The optimal FAPC electrode exhibited a high specific capacitance of 378 F/g at a specific current of 1 A/g and an excellent rate capability(271 F/g at 10 A/g),which are comparable or even superior to that of most reported carbon candidates.Furthermore,the FAPC-based device achieved a desired specific energy of 14.8Wh/kg at a specific power of 700W/kg.This work opens a new avenue to design metal-nanocluster materials for high-performance biomass waste-based supercapacitors.

Key words

Fe nanoclusters/Biomass waste/Porous carbon nanosheets/Supercapacitor/Charge transfer

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出版年

2024
中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

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影响因子:0.771
ISSN:1001-8417
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