首页|Molecular engineering towards dual surface local polarization sites on poly(heptazine imide)framework for boosting H2O2 photo-production
Molecular engineering towards dual surface local polarization sites on poly(heptazine imide)framework for boosting H2O2 photo-production
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The selective 2e-ORR reaction on polymeric carbon nitride framework is one of the most promising approaches for solar-driven hydrogen peroxide production.Poly(heptazine imide)(PHI)as a class of K+-incorporated crystalline carbon nitride framework,is highly active for photocatalytic H2O2 production.An upgrade on the H2O2 photoproduction performance of PHI is realized and the mechanistic insights are revealed in this work.By photochemical reaction,the electron withdrawing groups of hydroxyl group and cyano group are grafted on the surface of PHI frameworks.The dual polarization sites on the sur-face contribute significantly to the enhancement of the exciton dissociation.The optimized PHI with dual polarization sites exhibits a remarkable photocatalytic H2O2 production performance,which is 2 times of the active pristine PHI.Most importantly,the photochemical reaction method is generally applicable to improve the exciton dissociation of a wide range of polymeric carbon nitride frameworks with vari-ous structure and compositions;and the thiourea-derived polymeric carbon nitride framework with dual surface polarization sites exhibits a remarkable photocatalytic performance with a high H2O2 production rate of 40.5 mmol h-1 g-1.
Key Laboratory for Water Quality and Conservation of the Pearl River Delta,Ministry of Education,Institute of Environmental Research at Greater Bay,Guangzhou University,Guangzhou 510006,China
Department of Environmental Science and Engineering,Guangzhou University,Guangzhou 510006,China
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