Abstract
X-ray detection plays a crucial role across various aspects of our daily lives,encompassing medical diag-noses,security screenings,and non-destructive examinations in industrial settings.Given the wide array of application contexts,a wealth of opportunities is entailed with the practical utilization of both organic and inorganic X-ray detection materials.A novel and promising contender in this realm is the emergence of metal-free organic halide perovskites(O-PVSKs),offering great opportunities and tremendous potential in X-ray detection.This potential can be attributed to the distinct crystalline configuration of O-PVSKs,where organic constituents are structured into an ABX3 perovskite arrangement.Consequently,O-PVSKs exhibit captivating characteristics reminiscent of organic materials,such as lightweight nature and mod-ifiability,all while retaining the distinctive traits associated with halide perovskites ranging from diverse structures to tunable optoelectronic properties.This review article delves into the intrinsic attributes of O-PVSKs and critically examines the viability of O-PVSKs in X-ray detection,through which key features that distinguish O-PVSKs from traditional organic semiconductors and perovskites are outlined.This is followed by a perspective given on their future avenues for exploration.