首页|Covalently bonded ternary photocatalyst comprising MoSe2/black phosphorus nanosheet/graphitic carbon nitride for efficient moxifloxacin degradation

Covalently bonded ternary photocatalyst comprising MoSe2/black phosphorus nanosheet/graphitic carbon nitride for efficient moxifloxacin degradation

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Covalently bonded bridging between different semiconductors is a remarkable approach to improve the transfer of charge carriers at interfaces.In this study,we designed a ternary heterojunction(MBG)combining of molybdenum diselenide(MoSe2),black phosphorus nanosheets(Bpn)and graphitic car-bon nitride(GCN).Among this MBG of MoSe2/Bpn/GCN,(i)the covalently bonded bridging effect be-tween Bpn/GCN facilitates directional charge carrier transfer,meanwhile(ii)a Z-scheme heterojunction is formed between MoSe2/GCN to enhance the separation of photogenerated carriers.Furthermore,(iii)this composite exhibits an increased absorption for visible light.Using this MBG,photocatalytic degradation of over 98%of moxifloxacin is achieved within 20 min,with O2·-confirmed as the primary photocatalytic active species.These findings provide novel insights into the construction of efficient heterojunction by covalently bonded bridging.

Ternary heterojunctionBlack phosphorus nanosheetsCovalent bondPhotocatalytic degradationGraphitic carbon nitride

Yuhao Ma、Yufei Zhou、Mingchuan Yu、Cheng Fang、Shaoxia Yang、Junfeng Niu

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College of Environmental Science and Engineering,North China Electric Power University,Beijing 102206,China

College of Water Conservancy and Hydropower Engineering,North China Electric Power University,Beijing 102206,China

Global Centre for Environmental Remediation(GCER),University of Newcastle,Callaghan,NSW 2308,Australia

2024

中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCD
影响因子:0.771
ISSN:1001-8417
年,卷(期):2024.35(9)
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