首页|Supramolecular confinement effect enabling light-harvesting system for photocatalytic α-oxyamination reaction
Supramolecular confinement effect enabling light-harvesting system for photocatalytic α-oxyamination reaction
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维普
The supramolecular Förster resonance energy transfer(FRET)is seen as a promising approach for or-ganic photocatalysis using dyes as catalysts,because it combines the high efficiency of energy transfer with the dynamic responsiveness based on non-covalent interactions.Here we propose a supramolecu-lar FRET photocatalysis strategy for α-oxyamination reaction based on supramolecular confinement effect.The well-designed benzothiadiazole-based cationic monomer as energy donor and the dyes of Nile Red as acceptor are doped into the amphiphilic surfactants of sodium dodecyl sulfate(SDS).Benefitting from the supramolecular confinement space provided by SDS in aqueous environment,the FRET process between the monomer and Nile Red is effectively achieved(exciton migration rate:3.99 × 1014L mol-1 s-1).On this basis,the supramolecular FRET system is used as an efficient energy source to catalyze α-oxyamination reactions between a series of 1,3-dicarbonyl compounds and 2,2,6,6-tetramethylpiperidine-1-oxyl under white LED light,showing a yield as high as 94％and a turnover frequency value of 3.92 h-1.This photo-catalytic result shows a great enhancement compared to that of Nile Red alone.
Shaanxi Key Laboratory of Macromolecular Science and Technology,Xi'an Key Laboratory of Hybrid Luminescent Materials and Photonic Device,MOE Key Laboratory of Material Physics and Chemistry under Extraordinary Conditions,School of Chemistry and Chemical Engineering,Northwestern Polytechnical University,Xi'an 710072,China
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维普
