中国化学快报(英文版)2024,Vol.35Issue(11) :318-322.DOI:10.1016/j.cclet.2024.109927

Crown aldoxime ethers:Their synthesis,structure,acid-catalyzed/photo-induced isomerization and adjustable guest binding

Yulin Mao Jingyu Ma Jiecheng Ji Yuliang Wang Wanhua Wu Cheng Yang
中国化学快报(英文版)2024,Vol.35Issue(11) :318-322.DOI:10.1016/j.cclet.2024.109927

Crown aldoxime ethers:Their synthesis,structure,acid-catalyzed/photo-induced isomerization and adjustable guest binding

Yulin Mao 1Jingyu Ma 1Jiecheng Ji 2Yuliang Wang 1Wanhua Wu 1Cheng Yang1
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作者信息

  • 1. Key Laboratory of Green Chemistry & Technology of Ministry of Education,College of Chemistry,Sichuan University,Chengdu 610065,China
  • 2. Laboratory of Precision Cancer Therapeutics,Precision Medicine Research Center,West China Hospital,Sichuan University,Chengdu 610041,China
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Abstract

A series of novel crown aldoxime ethers were synthesized,demonstrating notable thermal and hydrolysis stability.The showcased acid-catalyzed and photo-induced cis/trans isomerization,which enables orthog-onal control over both guest complexation and the chiroptical effects of these crown aldoxime ethers,manifesting a regulation of complexation through isomerization at binding heteroatoms.

Key words

Crown aldoxime ether/Cis/trans isomerization/Photoisomerization/Chiroptical induction/Orthogonal control

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出版年

2024
中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

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影响因子:0.771
ISSN:1001-8417
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