首页|Crown aldoxime ethers:Their synthesis,structure,acid-catalyzed/photo-induced isomerization and adjustable guest binding
Crown aldoxime ethers:Their synthesis,structure,acid-catalyzed/photo-induced isomerization and adjustable guest binding
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A series of novel crown aldoxime ethers were synthesized,demonstrating notable thermal and hydrolysis stability.The showcased acid-catalyzed and photo-induced cis/trans isomerization,which enables orthog-onal control over both guest complexation and the chiroptical effects of these crown aldoxime ethers,manifesting a regulation of complexation through isomerization at binding heteroatoms.
Crown aldoxime etherCis/trans isomerizationPhotoisomerizationChiroptical inductionOrthogonal control
Yulin Mao、Jingyu Ma、Jiecheng Ji、Yuliang Wang、Wanhua Wu、Cheng Yang
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Key Laboratory of Green Chemistry & Technology of Ministry of Education,College of Chemistry,Sichuan University,Chengdu 610065,China
Laboratory of Precision Cancer Therapeutics,Precision Medicine Research Center,West China Hospital,Sichuan University,Chengdu 610041,China
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