首页|Visible-light-induced four-component difunctionalization of alkenes to construct phosphorodithioate-containing quinoxalin-2(1H)-ones

Visible-light-induced four-component difunctionalization of alkenes to construct phosphorodithioate-containing quinoxalin-2(1H)-ones

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A facile visible-light-induced 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4CzIPN)catalyzed four-component reaction of alkenes,quinoxalin-2(1H)-ones,P4S10 and alcohols has been developed at room temperature.This tandem reaction provides an efficient strategy for the construction of various phosphorodithioate-containing quinoxalin-2(1H)-ones with moderate to good yields by using air(dioxy-gen)as the green oxidant.Experimental studies revealed a radical process was involved in this photo-chemical reaction.

Visible-light catalysisFour-component reactionPhosphorodithioateQuinoxalin-2(1H)-ones

Xiao-Ming Chen、Lianhui Song、Jun Pan、Fei Zeng、Yi Xie、Wei Wei、Dong Yi

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Department of Biology and Chemistry,Hunan University of Science and Engineering,Yongzhou 425199,China

School of Chemistry and Chemical Engineering,Qufu Normal University,Qufu 273165,China

Green Pharmaceutical Technology Key Laboratory of Luzhou City,School of Pharmacy,Southwest Medical University,Luzhou 646000,China

2024

中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCD
影响因子:0.771
ISSN:1001-8417
年,卷(期):2024.35(11)