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温度对果糖含量近红外光谱检测模型传递的影响

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以果糖溶液为研究对象,采用斜率/截距(S/B)算法,通过不同温度的果糖含量检测模型在两台不同厂家的傅里叶变换近红外光谱仪间的传递,讨论了样品温度变化对模型传递的影响。主、从仪器直接建模时,预测集的均方根偏差(RMSEP)均随温度升高呈增大的趋势,但整体变化不显著。直接预测时,预测集的RMSEP均大于0。86,效果不理想;采用S/B算法传递后,预测结果得到改善,主、从仪器相同温度光谱间的传递结果优于不同温度光谱间的传递,15℃、22℃和28℃时相同温度光谱间传递后的RMSEP分别为0。317、0。389和0。416,差异显著。实验结果表明,进行模型传递时,样品温度变化会对模型传递产生较大影响;保证样品温度一致下,选择合适温度有利于取得最佳传递效果。
Influence of temperature on calibration transfer of near-infrared spectroscopy detection model for fructose content
The method of Slope/Bias correction was applied to study the calibration transfer of the fructose content detection model at different sample temperatures between two different fourier-transformation near-infrared spectrometer machines. The effect of the sample temperature on the result of calibration transfer was discussed. When modeled directly on the master and slave instruments, the root mean square of prediction error (RMSEP) of the prediction set each had a rising trend with the increase of temperature. But the change was not significant. When predicted directly, the results all were greater than 0. 86, thus being unsatisfactory. After transfer by S/B algorithm, the RMSEP was improved. The transfer result between the same temperature spectra was better than between the different. When transferred between the same temperature spectra, the results of 15℃,22 ℃ and 28 ℃ were 0. 317, 0. 389 and 0. 416, the difference being significant. It is shown that temperature variation has great influence on model transfer. With consistent sample temperature on the master and slave instruments ensured, it is good to choose an appropriate temperature for achieving the best transfer result.

near-infrared spectroscopycalibration transferfructose contentcalibration transfer

周林峰、吕进、刘辉军、施秧、李博斌

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中国计量学院计量测试工程学院,浙江杭州310018

浙江科技学院自动化电气工程学院,浙江杭州310023

国家黄酒产品质量监督检验中心,浙江绍兴312071

近红外光谱 模型传递 果糖含量 样品温度

浙江省重大科技专项和优先主题项目浙江省科技计划项目

2010C110602012C21010

2012

中国计量大学学报
中国计量学院

中国计量大学学报

CHSSCD
影响因子:0.357
ISSN:2096-2835
年,卷(期):2012.23(3)
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