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尿素水解制氨的燃煤电站SCR系统喷氨控制优化

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目的:研究尿素水解制氨下的燃煤电站SCR系统喷氨支管优化控制方案,并分析其应用效果。方法:基于AspenPlus模拟尿素水解系统,分析氨气变化特性;结合工程应用完成SCR系统喷氨控制优化,并利用投运前后实际运行数据建立针对性评估方案分析控制优化效果。结果:模拟发现,反应温度、反应压力、尿素进料质量分数都有助于提高产品气中氨气的体积分数。SCR系统喷氨控制优化后,选取投运前后两段运行时间内运行参数进行分析,计算SCR系统平均氨耗率,发现投运后较投运前下降28。13%;比较两段运行时间内同一锅炉蒸发量和入口 NOx质量浓度下平均氨耗量发现,投运后较投运前下降30。27%。结论:尿素水解制氨的燃煤电站SCR系统喷氨控制优化方案可以提升机组的脱硝性能并降低系统氨耗量。
Optimization of ammonia injection control in the SCR system of coal-fired power stations for ammonia production by urea hydrolysis
Aims:This paper aims to optimize the control scheme of ammonia injection branch pipes of the SCR system of coal-fired power stations under urea hydrolysis to produce ammonia with its application effect analyzed.Methods:The urea hydrolysis system based on Aspen Plus was simulated;and the ammonia change characteristics were analyzed.The ammonia injection control optimization of the SCR system was completed in combination with engineering applications;and a targeted evaluation scheme to analyze the control optimization effect was established by using the actual operation data before and after the commissioning.Results:The simulation found that the reaction temperature,reaction pressure,and urea feed mass fraction all helped to increase the volume fraction of ammonia in the product gas.After the optimization of the ammonia injection control of the SCR system,the operating parameters of the SCR system before and after the commissioning of the two periods of time were selected for analysis.Through the calculation of the average ammonia consumption rate of the SCR system it was found that the average ammonia consumption rate of the SCR system decreased by 28.13% compared with that of the pre-commissioning after the commissioning of the SCR system,and the average ammonia consumption rate decreased by 30.27% after the commissioning of the SCR system compared with the average ammonia consumption rate of the SCR system in the two periods of time under the same evaporation rate of the boiler and the same concentration of the inlet NOx.Comparing the average ammonia consumption of the same boiler evaporation rate and the inlet NOx concentration during the two operation periods,it was found that the average ammonia consumption after commissioning was 30.27% lower than that before commissioning.Conclusions:The optimized control scheme of ammonia injection in the SCR system of coal-fired power stations with ammonia hydrolysis from urea can improve the denitrification performance of the unit and reduce the ammonia consumption of the system.

urea hydrolysis systemSCR systemammonia injection optimizationchemical reactionammonia-nitrogen mixing equivalent ratio

张裕、王琦、沈德魁

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中国计量大学计量测试与仪器工程学院,浙江杭州 310018

东南大学能源与环境学院,江苏南京 210096

尿素水解系统 SCR系统 喷氨优化 化学反应 氨氮混合当量比

国家自然科学基金资助项目浙江省科技计划项目

319717962022C02002

2024

中国计量大学学报
中国计量学院

中国计量大学学报

CHSSCD
影响因子:0.357
ISSN:2096-2835
年,卷(期):2024.35(2)