首页|HEMA接枝改性天然胶乳的制备及其粘接性能研究

HEMA接枝改性天然胶乳的制备及其粘接性能研究

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以甲基丙烯酸羟乙酯(HEMA)作为天然胶乳(NRL)的接枝改性剂,采用乳液聚合法制备了NR-g-HEMA[HEMA接枝NR(天然橡胶)]胶乳;然后以此为基体,并以水溶性松香树脂为增黏树脂、邻苯二甲酸二丁酯(DBP)为增塑剂等,制备相应的NR-g-HEMA胶粘剂;最后,用该胶粘剂压制胶合板,并对胶合板的粘接性能进行了测定.结果表明:采用单因素试验法优选出制备NR-g-HEMA胶乳的最佳工艺条件为m(干态单体)∶m(NRL)∶m(引发剂)∶m(活化剂)∶m(交联剂)=20∶100∶0.2∶0.2∶0.1、反应时间为8h和反应温度为16℃,此时相应胶合板的剪切强度(1.88MPa)符合Ⅲ类胶合板的指标要求.
Study on preparation and bonding properties of natural rubber latex grafted and modified by HEMA
Abstract:With hydroxyethyl methacrylate (HEMA) as graft modifier of natural rubber latex (NRL),a NR-g-HEMA[NR(natural rubber) grafted by HEMA] latex was prepared by emulsion polymerization.Then,with NR-g-HEMA latex as matrix,water-soluble rosin resin as tackifying resin,and dibutyl phthalate(DBP) as plasticizer,a corresponding NR-g-HEMA adhesive was prepared.Finally,the plywood was pressed by the adhesive,and the bongding properties of plywood were mensurated.The results showed that the optimal process conditions of preparing NR-g-HEMA latex were preferred by single-factor experiment method when mass ratio of m(dry monomer)∶m(NRL)∶m(initiator)∶m(activating agent)∶m(cross linker) was 20∶100∶0.2∶0∶2∶0.1,reaction time was 8h and reaction temperature was 16℃.Here,the shear strength (1.88MPa) of corresponding plywood could meet index requirement of Ⅲ class-plywood.

natural rubber (NR)graft modificationhydroxyethyl methacrylate (HEMA)adhesiveshear strength

卫飞云、刘宏超、曹端林、余和平

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中国热带农业科学院农产品加工研究所,广东湛江524001

中北大学化工与环境学院,山西太原030051

天然橡胶 接枝改性 甲基丙烯酸羟乙酯 胶粘剂 剪切强度

科技部科研院所技术开发专项基金

2011EG134220

2013

中国胶粘剂
上海市合成树脂研究所 全国粘合剂信息站 中国胶粘剂和胶粘带工业协会

中国胶粘剂

CSTPCD北大核心
影响因子:0.522
ISSN:1004-2849
年,卷(期):2013.22(6)
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