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掺配高苯乙烯含量SIS对热熔压敏胶性能影响

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以台橡SIS 4113作为SIS基热熔压敏胶热嵌段共聚物主体,掺配两种高苯乙烯含量SIS 4211和4411,通过熔融混合法制备SIS型热熔压敏胶.考察了不同高苯乙烯SIS掺配量变化对热熔压敏胶基础性能、黏着特性及流变性能的影响.研究结果表明:(1)随着掺混4211及4411比例的提高,热熔压敏胶的黏度降低、软化点升高,且掺混4411效果变化尤其明显,对于黏着性能、高温持粘性、剪切破坏温度均明显提升.(2)掺混4211的环形初粘力、180°剥离力稍有波动;而掺混4411对润湿性能影响较大,环形初粘力及180°剥离力均有明显降低.(3)流变曲线显示,掺混比例升高后,玻璃化转变温度(Tg)点及流动点逐渐升高,储能模量明显升高,与高温持粘测试结果对应.
The influence of adding SIS with high styrene content on the performance of hot melt pressure sensitive adhesive
Using TSRC SIS 4113 as the main body of hot block copolymer of SIS-based hot melt pressure sensitive adhesive,two kinds of SIS 4211 and 4411 with high styrene content were blended,and SIS type hot melt pressure sensitive adhesive was prepared by melt mixing method.The influence of different contents of SIS with high styrene on the basic properties,adhesion properties,and rheological properties of hot melt pressure sensitive adhesive was investigated.The research results showed that,(1)With the increase of the ratio of 4211 and 4411,the viscosity of hot melt pressure sensitive adhesive decreased and the softening point increased,while the effect of mixing 4411 changed significantly,the adhesion performance,high-temperature holding power,and shear failure temperature were all significantly improved.(2)The loop tack and 180°peel force after blending 4211 had slight fluctuations,the addition of 4411 had a significant impact on the wetting performance,with a significant decrease in the loop tack and 180°peel force.(3)The rheological curves showed that as the blending ratio increased,the glass transition temperature(Tg)point and flow point gradually increased,and the storage modulus significantly increased,corresponding to the results of the high-temperature holding power test.

SIS with high styrene contenthot melt pressure sensitive adhesiveadhesion performancerheological performance

朱金柱、曹秀生、冒弘、周建东

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台橡(南通)实业有限公司,江苏南通 226017

台橡宇部(南通)化学工业有限公司,江苏南通 226017

高苯乙烯含量SIS 热熔压敏胶 黏着性能 流变性能

2024

中国胶粘剂
上海市合成树脂研究所 全国粘合剂信息站 中国胶粘剂和胶粘带工业协会

中国胶粘剂

CSTPCD
影响因子:0.522
ISSN:1004-2849
年,卷(期):2024.33(1)
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