首页|KH-560改性钡酚醛树脂的制备及性能研究

KH-560改性钡酚醛树脂的制备及性能研究

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为改善钡酚醛树脂的耐高温性能和力学性能,本研究采用硅烷偶联剂KH-560对钡酚醛树脂进行化学改性.对改性前后的树脂进行了各项性能表征,重点研究了该改性树脂的热稳定性、力学性能和附着力.研究结果表明:(1)成功地将KH-560通过化学键稳定地连接到钡酚醛树脂的分子链上;(2)KH-560的较佳添加量为15%,相比于纯钡酚醛树脂,改性后钡酚醛树脂的Tmax2提高了约25 ℃,热性能提升明显;(3)KH-560能够有效改善钡酚醛树脂的力学性能,15%含量的KH-560改性钡酚醛树脂的拉伸强度提高约32.5%,拉伸模量提高约11.7%,附着力提高约30.4%.
Preparation and performance study of barium phenolic resin modified by KH-560
In order to improve the high-temperature resistance and mechanical properties of barium phenolic resin,silane coupling agent KH-560 was used to chemically modify the resin in this study.Various performance characterizations were conducted on the resin before and after modification,with a focus on the thermal stability,mechanical properties,and adhesion of the modified resin.The research results showed that,(1)KH-560 was successfully and stably connected to the molecular chain of barium phenolic resin through chemical bonds.(2)The optimal addition amount of KH-560 was 15%.Compared with pure barium phenolic resin,the Tmax2 of modified barium phenolic resin increased by about 25 ℃,and the thermal performance was significantly improved.(3)KH-560 could effectively improve the mechanical properties of barium phenolic resin.The tensile strength of barium phenolic resin modified by 15%of KH-560 increased by about 32.5%,the tensile modulus increased by about 11.7%,and the adhesion increased by about 30.4%.

KH-560barium phenolic resinmodificationthermal stabilitytensile propertyadhesion

李盼盼、刘晓丽、高国胜、段万泽、张乐、赵建宇

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北京新风航天装备有限公司,北京 100854

KH-560 钡酚醛树脂 改性 热稳定性 拉伸性能 附着力

2024

中国胶粘剂
上海市合成树脂研究所 全国粘合剂信息站 中国胶粘剂和胶粘带工业协会

中国胶粘剂

CSTPCD
影响因子:0.522
ISSN:1004-2849
年,卷(期):2024.33(3)
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