首页|新型高性能环氧防弹胶粘剂的研制

新型高性能环氧防弹胶粘剂的研制

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采用两种环氧树脂(多官能环氧树脂SINEP E80、环氧树脂SRTEM-50)与聚砜树脂(SE3940)、环氧扩链剂等,添加多种环氧增韧剂,再加入固化剂和促进剂,制得4种环氧胶粘剂体系,并对其性能进行综合分析。研究结果表明:(1)4种不同增韧剂配比的环氧胶粘剂中,PEJ-3黏度适中,便于涂覆于纤维,且表观活化能较低,固化反应速率较快。(2)4种配方环氧胶粘剂的电容随着频率增加而缓慢下降,其中PEJ-2、PEJ-3、PEJ-4配方胶粘剂的电容在4。6~5。4之间,均具有良好的电容稳定性。4种不同增韧剂配比的环氧胶粘剂,其介电损耗随着频率的增加而增加,在外加电场下,4种配方表现出良好的电气绝缘性能。(3)4种配方的环氧胶粘剂在中低温区均表现出优异的剪切性能。其中,PEJ-3在测试范围-60~190℃仍能保持较高的拉伸剪切强度,该配方具有较好的粘接强度和耐高低温性能,可满足防弹复合材料的树脂基强度及耐热性能的基本需求。(4)4个配方的吸水率均体现出良好的疏水性能,在0。20%~0。60%之间。这一特性使其在需要防水、防潮的场合具有广泛的应用前景。(5)PEJ-3配方复合材料含胶量为37。4%,在射击测试中,未被击穿。凹陷深度仅有18 mm,小于标准的25 mm,说明该环氧胶粘剂以及纤维与树脂复合工艺能够研制出综合性能优异的防弹复合材料。
Development of new high-performance epoxy adhesive for bulletproof
Four types of epoxy adhesive systems were prepared by using two types of epoxy resin(multifunctional epoxy resin SINEP E80,epoxy resin SRTEM-50),polysulfone resin(SE3940),epoxy chain extender,etc.,adding various epoxy toughening agents,and then adding curing agents and accelerators,and their properties were comprehensively analyzed.The research results showed that,(1)Among the four types of epoxy adhesive with different toughening agent ratios,PEJ-3 had moderate viscosity,making it easy to coat onto fibers,and had a lower apparent activation energy and faster curing reaction rate.(2)The capacitance of the four formulations of epoxy adhesive slowly decreased with increasing frequency,among which the capacitance of PEJ-2,PEJ-3,and PEJ-4 formulations of adhesive was between 4.6 and 5.4,all of which had good capacitance stability.The dielectric loss of four types of epoxy adhesive with different toughening agent ratios increased with frequency.Under an external electric field,the four formulations exhibited good electrical insulation performance.(3)The four formulations of epoxy adhesive exhibited excellent shear performance in the medium to low temperature range.Among them,PEJ-3 could still maintain high tensile shear strength within the testing range of-60 to 190℃.This formulation had good bonding strength and high and low temperature resistance,which could meet the basic requirements of resin-based strength and heat resistance of bulletproof composite materials.(4)The water absorption rates of four formulations all demonstrated good hydrophobicity,ranging from 0.20%to 0.60%.This characteristic made it widely applicable in situations where waterproofing and moisture resistance were required.(5)The PEJ-3 formulation composite material had an adhesive content of 37.4%and was not penetrated during the shooting test.The depression depth was only 18 mm,which was less than the standard 25 mm,indicating that the epoxy adhesive and fiber resin composite process could develop bulletproof composite materials with excellent comprehensive performance.

high-temperature resistancelow-temperature resistanceepoxy resin adhesivebulletproof composite materialsadhesive performance

李亚东、潘秀兰、虞鑫海

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东华大学化学与化工学院,上海 201620

耐高温 耐低温 环氧树脂胶粘剂 防弹复合材料 胶粘剂性能

2024

中国胶粘剂
上海市合成树脂研究所 全国粘合剂信息站 中国胶粘剂和胶粘带工业协会

中国胶粘剂

CSTPCD
影响因子:0.522
ISSN:1004-2849
年,卷(期):2024.33(12)