首页|苯醚甲环唑在芹菜及其土壤中的残留测定和消解动态研究

苯醚甲环唑在芹菜及其土壤中的残留测定和消解动态研究

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采用气相色谱-电子捕获检测,对芹菜及其土壤中的苯醚甲环唑消解动态和最终残留量进行了研究,评价了苯醚甲环唑在芹菜上使用后的残留行为和环境安全性.苯醚甲环唑在芹菜及土壤中的残留消解动态均符合一级动力学方程,苯醚甲环唑在芹菜上消解快;苯醚甲环唑最终残留量与施药的剂量、施药次数及采样的间隔时间有关;水解研究表明,苯醚甲环唑是稳定的农药,在不同温度和不同pH的研究条件下水解半衰期均大于166 d,碱性条件更有利于苯醚甲环唑的降解.
Study on determination and dynamics of difenoconazole residues in celery and soil
In order to formulate the standards for safe application of difenoconazole in celery, an analytical method was developed using gas chromatography with electron capture detector for the detection and dynamics of the residues of difenoconazole in this paper.The applications of difenoconazole in celery and soil were discussed to evaluate residue behavior and environmental safety of difenoconazole.The results of residual dynamics showed that the dissipation rates of difenoconazole in celery and soil all followed the first order kinetics.The results of the final residue assay indicated that the residue levels of difenoconazole in celery and soil all increased as the application dosage and application times increased, or as the harvest interval decreased.The results of hydrolysis showed that the degradation of difenoconazole in buffer solutions was difficult.The half-life of difenoconazole in solution was more than 166 d.The difenoconazole is degraded easier in basic solution.

difenoconazoledynamicsresiduehydrolysishalf-life

初春、王志华、秦冬梅、龚勇、季颖

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化工资源有效利用国家重点实验室,北京化工大学理学院,北京100029

农业部农药检定所,北京100026

苯醚甲环唑 消解动态 残留 水解 半衰期

2011

中国科学(化学)
中国科学院

中国科学(化学)

CSTPCDCSCD北大核心
影响因子:0.685
ISSN:1674-7224
年,卷(期):2011.41(1)
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