首页|PM6:Y6基三元有机太阳能电池研究进展

PM6:Y6基三元有机太阳能电池研究进展

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有机太阳能电池(OSCs)因具有质轻、柔性、可印刷制备等优点受到广泛的关注.近年来,由于新型给受体材料的研发,OSCs的能量转换效率已经有了很大的突破.特别是基于宽带隙聚合物PM6和新型非富勒烯受体Y6构筑的二元OSCs的效率高达15.7%,这使得PM6:Y6基OSCs成为研究热点.由于二元OSCs的活性层对太阳光谱的吸收相对有限,限制了器件性能的进一步提升.通过引入吸收互补的第三组分构建三元OSCs被证明是提高器件性能的一种非常有效的策略.基于三元策略,PM6:Y6基OSCs的效率得到了大幅提升.因此,有必要全面总结PM6:Y6基三元OSCs的研究进展.本文介绍了三元OSCs的工作机制,探究了第三组分的作用和选取依据,重点综述了聚合物给体、小分子给体、富勒烯受体、非富勒烯受体作为第三组分构筑的PM6:Y6基OSCs的研究进展,并对未来PM6:Y6基三元OSCs的发展进行了展望.
Research progress on PM6:Y6-based ternary organic solar cells
Organic solar cells(OSCs)have attracted extensive attention because of their unique merits in light-weight,high flexibility,and printability.In recent years,the PCEs of OSCs have undergone great breakthroughs due to the development of new donor/acceptor materials.In particular,a high PCE of 15.7%was achieved in the OSCs adopting a wide bandgap polymer of PM6 and a new emerging non-fullerene acceptor of Y6,which makes PM6:Y6-based OSCs a research hotspot.However,a critical disadvantage in binary OSCs is the relatively narrow optical absorption,which limits further improvements on the PCE.Constructing ternary OSCs by introducing the third components with complementary absorption into the binary hosts has been proven to be an effective way to improve the efficiency of OSCs.The performance of PM6:Y6-based OSCs were greatly improved using the ternary strategy.Therefore,a comprehensive review on the recent progress in PM6:Y6-based ternary OSCs is needed.In this paper,the working mechanism of ternary OSCs is introduced firstly.Meanwhile,the role and selection criteria of the third component in ternary OSCs are explored.The research progress of PM6:Y6-based ternary OSCs constructed by polymer donors,small molecule donors,fullerene acceptors and non-fullerene acceptors as the third component are emphatically summarized.Finally,the future development of PM6:Y6-based ternary OSCs is also discussed.

organic solar cellsternary strategyPM6Y6efficiency

刘芯辛、吴霞、王贤雨、马林宇珊、郭彪、赵震

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沈阳师范大学化学化工学院能源与环境催化研究所,沈阳 110034

中国石油大学(北京)重质油国家重点实验室,北京 102249

有机太阳能电池 三元策略 PM6 Y6 效率

国家自然科学基金辽宁省自然科学基金

222021352021-BS-157

2024

中国科学(化学)
中国科学院

中国科学(化学)

CSTPCD北大核心
影响因子:0.685
ISSN:1674-7224
年,卷(期):2024.54(2)
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