中国科学(化学)2024,Vol.54Issue(12) :2565-2579.DOI:10.1360/SSC-2024-0120

Fe基分子筛NH3-SCR脱硝催化剂的研究进展

Research progress in Fe-based molecular sieve NH3-SCR denitration catalyst

才博慧 安子静 王阅 杜妍 任利敏 殷成阳
中国科学(化学)2024,Vol.54Issue(12) :2565-2579.DOI:10.1360/SSC-2024-0120

Fe基分子筛NH3-SCR脱硝催化剂的研究进展

Research progress in Fe-based molecular sieve NH3-SCR denitration catalyst

才博慧 1安子静 1王阅 1杜妍 1任利敏 2殷成阳1
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作者信息

  • 1. 沈阳师范大学化学化工学院,能源与环境催化研究所,沈阳 110034
  • 2. 大连理工大学化学学院,大连 116023
  • 折叠

摘要

近年来,氮氧化物(NOx)已经成为大气的主要污染源之一.研究发现,选择性催化还原技术(SCR)的脱硝效率可达90%以上,特别是以NH3为还原剂的NH3-SCR技术是目前非常有效且应用最为广泛的脱硝技术.本文综述了Fe基分子筛脱硝催化剂在NH3-SCR反应中的研究进展,对其研究概况、制备方法、活性和稳定性的强化策略进行了总结概述,详细介绍了常见的Fe基分子筛催化剂如Fe-ZSM-5、Fe-Beta、Fe-CHA用于NH3-SCR反应的概况.通过合成不同拓扑结构的Fe基分子筛催化剂,向Fe基分子筛催化剂中引入不同种类金属以及构建核壳结构等强化策略来提高Fe基分子筛催化剂的NH3-SCR活性、水热稳定性以及抗中毒性能,最后对Fe基分子筛NH3-SCR催化剂脱硝性能与抗中毒性能不断提升以及工业化应用等方面的未来发展方向进行了展望.

Abstract

In recent years,nitrogen oxides(NOx)have become a major source of environmental pollution in the atmosphere.It is found that the denitration efficiency of selective catalytic reduction(SCR)technology can reach over 90%,especially the NH3-SCR technology with NH3 as the reducing agent,which is currently the most effective and widely used denitration technology.In this review,the research progress of Fe-based molecular sieve denitration catalysts in NH3-SCR reaction was reviewed,and their research overview,preparation methods and activity and stability strengthening strategies were summarized.The common Fe-based molecular sieve catalysts such as Fe-ZSM-5,Fe-Beta and Fe-CHA used in NH3-SCR reaction were introduced in detail.The NH3-SCR activity,hydrothermal stability,and anti-poisoning performance of Fe-based molecular sieve catalysts were improved by strengthening strategies for synthesizing different topological structures of Fe-based molecular sieve catalysts,introducing different types of metals into Fe-based molecular sieve catalysts and constructing core-shell structures.Finally,the future development directions of Fe-based molecular sieve NH3-SCR catalysts in terms of denitration efficiency and anti-poisoning performance,as well as industrial applications,were prospected.

关键词

铁基/分子筛/催化剂/氨气选择性催化还原/氮氧化物脱除

Key words

Fe-based/molecular sieve/catalyst/NH3-SCR/denitration

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出版年

2024
中国科学(化学)
中国科学院

中国科学(化学)

CSTPCD北大核心
影响因子:0.685
ISSN:1674-7224
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