首页|碱激发矿渣基泡沫混凝土的制备及其封存CO2可行性研究

碱激发矿渣基泡沫混凝土的制备及其封存CO2可行性研究

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随着工业化进程的不断推进,工业固体废弃物的排放量逐年增加,以工业固废为主要原料制备泡沫混凝土并将其用于CO2 封存,对实现工业固废的资源化利用和CO2 的经济、高效封存具有重要意义.本文以高炉矿渣为原料,选用NaOH为碱激发剂,硬脂酸钠为稳泡剂,十二烷基硫酸钠(C12H25NAO4S,SDS)为发泡剂,制备了高孔隙的泡沫混凝土.探究了不同NaOH用量对矿渣基泡沫混凝土综合性能及封存CO2 性能的影响.实验结果表明,随着NaOH用量的增加,泡沫混凝土的干密度逐渐增加,抗压强度先增大后减小.泡沫混凝土的内部孔隙分布不均匀,孔隙率大.SEM结果表明,当NaOH用量过高时泡沫发生破裂连通.XRD结果表明,矿渣基泡沫混凝土水化产物主要是C—S—H凝胶和Ht物相,Ht物相的层状结构使得材料的孔壁不够致密,从而影响材料的力学性能.TGA结果表明,碳化过程中水化产物有效吸收CO2 转化成以CaCO3 为主的碳酸盐,NaOH用量 12%时,CO2 的封存量最高为89.74 kg/m3.
Preparation of alkali-activated slag based foam concrete and feasibility study on CO2 sequestration
With the continuous advancement of industrialization process,the scale of industrial solid waste is also expanding.Foam concrete has great development potential in CO2 sequestration.Therefore,it is of great significance for industrial solid waste for resource utilization and the economic and efficient storage of CO2.In this paper,high-porosity foamed concrete is prepared using blast furnace slag as the raw material,NaOH as the alkali activator,sodium stearate as a foam stabilizer,and sodium dodecyl sulfate(C12H25NAO4S,SDS)as the foaming agent.The influence of different NaOH content on the comprehensive performance of slag based foam concrete and CO2 sequestration performance is investigated.The experimental results show that the dry density of foam concrete increases gradually with the increase of NaOH content.When the amount of NaOH is 12%,the compressive strength starts to decrease.The internal pore distribution of foam concrete is uneven,and the porosity is large.SEM results show that when the amount of NaOH is too high,the foam will break and connect,which will increase the proportion of macropores.XRD results show that the hydration products of slag based foam concrete are mainly C—S—H gel and Ht phase.The layered structure of Ht phase makes the pore wall of the material not dense enough,thus affecting the mechanical properties of the material.TGA results show that the hydrated products can effectively absorb CO2 and transform it into carbonate dominated by CaCO3.When the amount of NaOH is 12%,the maximum sequestration capacity of CO2 is 89.74 kg/m3.

alkali-activatedslagfoam concreteCO2 sequestration

刘健、李伟、王立才、范建国、刘强、曹晓强、程卫民、王刚、关天举、宋长勇

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山东能源集团有限公司,山东 济南 250101

山东鲁西发电有限公司,山东 济宁 272000

山东科技大学安全与环境工程学院,山东 青岛 266590

碱激发 矿渣 泡沫混凝土 封存CO2

国家自然科学基金山东省自然科学基金会项目山东省自然科学基金青年项目山东省自然科学基金青年项目国家级大学生创新创业训练计划

52074176ZR2020ME106ZR2021QE067ZR2021Q1208202110424171

2024

中国矿业
中国矿业联合会

中国矿业

CSTPCD北大核心
影响因子:0.875
ISSN:1004-4051
年,卷(期):2024.33(1)
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