中国粮油学报2024,Vol.39Issue(1) :141-147.DOI:10.20048/j.cnki.issn.1003-0174.000154

富含高溶性β-胡萝卜素油脂体系氧化稳定性及降解动力学研究

Study on Oxidative Stability and Degradation Kinetics of Oil System Rich in Highly Soluble β-carotene

孙新怡 孙清瑞 李秀波 金丽梅
中国粮油学报2024,Vol.39Issue(1) :141-147.DOI:10.20048/j.cnki.issn.1003-0174.000154

富含高溶性β-胡萝卜素油脂体系氧化稳定性及降解动力学研究

Study on Oxidative Stability and Degradation Kinetics of Oil System Rich in Highly Soluble β-carotene

孙新怡 1孙清瑞 2李秀波 1金丽梅2
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作者信息

  • 1. 黑龙江八一农垦大学食品学院,大庆 163319
  • 2. 黑龙江八一农垦大学食品学院,大庆 163319;国家杂粮工程技术中心,大庆 163319
  • 折叠

摘要

为研究富含高溶性β-胡萝卜素的油脂体系(β-胡萝卜素总顺式质量分数约40%,其油脂基含量约10 mg/mL)的氧化稳定性及降解规律,在不同储藏温度(-18、4、20、37 ℃)下,以过氧化值为评价指标,首先通过建立降解动力学方程考察了富含高溶性β-胡萝卜素的不同油脂(大豆油、橄榄油、月见草油、鱼油)的氧化稳定性,同时进一步探讨了橄榄油中β-胡萝卜素及其异构体的储藏氧化降解规律.结果表明:高溶性β-胡萝卜素在不同油脂体系中的抗氧化效果依次为:橄榄油>大豆油>月见草油>鱼油;且在伴随储藏过程中,β-胡萝卜素的降解符合一级动力学模型规律,橄榄油中β-胡萝卜素异构体稳定性高低次序为:All-E>Total Z>13Z,且随着β-胡萝卜素异构体的氧化降解导致的其总含量减少,橄榄油的过氧化值也不断增大,表明高溶性β-胡萝卜素抗油脂氧化的效能降低.

Abstract

In order to investigate the oxidative stability and degradation patterns of oil systems rich in highly sol-uble β-carotene(the total cis-β-carotene accounted for about 40%,and its oil-based content was about 10 mg/mL,peroxide value was used as an evaluation index,the oxidative stability of different oils(soybean oil,olive oil,evening primrose oil and fish oil)rich in highly soluble β-carotene was first investigated by establishment of degradation kinetic equations at different storage temperatures(-18,4,20,37 ℃).Storage oxidative degrada-tion patterns of β-carotene and its isomers in olive oil were also further investigated.The results indicated that the antioxidant effects of highly soluble β-carotene in different oil systems were in the following order:olive oil>soybean oil>evening primrose oil>fish oil;the degradation of β-carotene during concomitant storage was in accordance with the first-order kinetic model;the order of stability of β-carotene isomers in olive oil was:All-E>Total Z>13 Z,and with the total content of β-carotene isomers decreased due to oxidative degradation,the peroxide value of olive oil also increased,indicating that the effectiveness of highly soluble β-carotene against lip-id oxidation was reduced.

关键词

β-胡萝卜素/油脂/氧化稳定性/降解动力学/异构体

Key words

β-carotene/oil/oxidative stability/degradation kinetics/isomers

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基金项目

黑龙江八一农垦大学博士人员科研启动基金项目(XDB-2017-15)

出版年

2024
中国粮油学报
中国粮油学会

中国粮油学报

CSTPCDCSCD北大核心
影响因子:1.056
ISSN:1003-0174
被引量1
参考文献量21
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