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不同磷酸盐对高水分挤压前后蛋白流变特性的影响研究

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为探究不同磷酸盐对物料在高水分挤压过程中流变行为的影响,进而分析物料中大分子的变性以及结构重新形成的机理,本研究以大豆分离蛋白、谷朊粉、小麦淀粉为原料,考察3种磷酸盐(NaH2PO4、Na2HPO4、Na3PO4)对高水分挤压原料流变学特性以及产品冻干粉流变学特性和粒径的影响.结果显示:3种磷酸盐都提高了原料粉在室温下(25℃)的流动性,其中NaH2PO4提高了样品G'、G",Na2HPO4、Na3PO4反之.3种磷酸盐都降低了冻干粉在室温下的G'、G"、表观黏度,并减弱了剪切稀化效应,其中Na3PO4大幅提高了样品tanδ值.在温度扫描中,磷酸盐降低了原料粉和冻干粉在受热凝胶化后的结构强度,其中Na3PO4提高了样品在降温阶段的流动性,NaH2PO4、Na2HPO4反之.相应的,Na3PO4使样品的粒径曲线右移,NaH2PO4、Na2HPO4反之.添加磷酸盐能显著影响物料在挤压过程中的流动行为,从而改变挤压产品品质.
Effects of Different Phosphates on Rheological Properties of Protein with/without High Moisture Extrusion
In order to explore the effects of different phosphates on the rheological behavior of materials during high-moisture extrusion,and then analyze the mechanism of macromolecular denaturation and structural reconstruc-tion in materials,soybean protein isolate,wheat gluten and wheat starch were used as the main raw materials in this study.The effects of three phosphates(NaH2PO4,Na2HPO4 and Na3PO4)on the rheological properties of raw mate-rials and the rheological properties and particle size of freeze-dried powder were investigated.The results indicated that the three phosphates all improved the fluidity of the raw material powder at room temperature(25 ℃).Among them,NaH2PO4 increased G'and G"of the samples,while Na2HPO4 and Na3PO4 were the opposite.The three phos-phates reduced G'and G"and apparent viscosity of the freeze-dried powder at room temperature and weakened the shear thinning effect.Among them,Na3PO4 greatly increased the tanδ value of the sample.In the temperature scan-ning,phosphate reduced the structural strength of the raw material powder and the freeze-dried powder after heat gelation.Among them,Na3PO4 increased the fluidity of the sample during the cooling stage,and NaH2PO4 and Na2HPO4 were the opposite.Correspondingly,Na3PO4 shifted the particle size curve of the sample to the right,while NaH2PO4 and Na2HPO4 shifted to the opposite.In summary,the addition of phosphate can significantly affect the flow behavior of the material during the extrusion process,thereby changing the quality of the extruded product.

extrusion textured proteinhigh moisture extrusionrheological propertiesparticle size

安红周、全鹏飞、郭益廷、黄山、李盘欣、黄亚男

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河南工业大学粮油食品学院,郑州 450001

小麦和玉米深加工国家工程研究中心,郑州 450001

河南省南街村(集团)有限公司,临颍 462600

磷酸盐 高水分挤压 流变特性 粒径

河南工业大学高层次人才科研启动基金项目小麦和玉米深加工国家工程实验室开放课题项目

2021BS038NL2022014

2024

中国粮油学报
中国粮油学会

中国粮油学报

CSTPCD北大核心
影响因子:1.056
ISSN:1003-0174
年,卷(期):2024.39(9)
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