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茶渣碱提果胶的流变性质及其食用膜的制备

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茶渣中含有约10%的果胶,用碱法提取的果胶产物(ATRP)可作为食用薄膜原料.以ATRP为原料,测定其基本组分,探究果胶质量浓度和添加Ca2+浓度对ATRP流变性质的影响.以ATRP为基材,分别添加海藻酸钠、魔芋葡甘聚糖和羧甲基纤维素钠制备果胶薄膜,探究其抗拉伸延展性的变化.结果表明,ATRP中主链HG结构域占比为72.3%,支链RG-I结构域占比为24.0%,其溶液为非牛顿流体.当ARTP质量浓度达70g/L时,其溶液黏度为5×104mPa·s,形成凝胶的储存模量(G')为157 Pa,损耗模量(G")为21 Pa,凝胶转换点在300 s-1处出现.与40 g/L ARTP溶液相比,其黏度和凝胶强度显著提高.此外,在40 g/L的ARTP溶液中添加Ca2+后,其黏度和凝胶强度的最高幅度分别可达到原始值的80倍和20倍,而其添加量不超过30 mmol/L.与单一 ATRP薄膜相比,复合薄膜具有更完整的外观与更优异的抗拉伸延展性.其中,ATRP-魔芋葡甘聚糖按体积比1∶1制备的复合薄膜的抗拉伸延展性最强,最大承受拉力为280 g(拉伸时间为70s),是单一 ATRP薄膜最大承受拉力的7倍,最大延展性的70倍.
Rheological Properties of Alkali-extracted Pectin from Tea Residue and Preparation of Its Edible Film
Tea residue contains approximately 10%pectin,which has the potential to serve as a raw material for edible film production.In this study,alkali-extracted tea residue pectin(ATRP)was employed that its basic composition was determined,and the influence of pectin concentration and the addition of Ca2+on the rheological properties of ATRP was investigated.Edible films were prepared using ATRP as the matrix material,combined with sodium alginate,konjac glu-comannan,and sodium carboxymethyl cellulose,to explore the changes in tensile elongation.The results showed that the ATRP contained 72.3%HG domain,while the side chain'RG-I domain'accounted for 24.0%,and the solution exhibit-ed non-Newtonian fluid behavior.When the ATRP mass concentration reached 70 g/L,the viscosity of the solution was 5×104mPa.s,and the resulting gel showed a storage modulus(G')of approximately 157 Pa and a loss modulus(G")of approximately 21 Pa,and the gelation transition occurred at 300 s-1,demonstrating a significant increase in viscosity and gel properties compared to the 40 g/L ATRP solution.Furthermore,after adding Ca2+to a 40 g/L ARTP solution,the maximum increases in its viscosity and gel strength could reach 80 times and 20 times their original values,respectively.but the Ca2+concentration should not exceed 30 mmol/L.Compared to the film made by only ATRP,the films made by complex reagents exhibited improved appearance and superior tensile elongation properties.Among them,the film made by ATRP-konjac glucomannan(prepare according to a volume ratio of 1∶1)showed the highest tensile elongation,with a maximum load of 280 g(at a stretching time of 70s),which was seven times higher than that of film made by only ATRP and 70 times higher in terms of elongation.Therefore,ATRP exhibits promising potential as a raw material for edible film production.

tea residuepectinrheological propertiesfilm forming potential

彭莉莉、杨新、李伟强、王梦田、张晨

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福州大学生物科学与工程学院 福州 350108

福建省食品生物技术创新工程技术研究中心 福州 350108

福州市青瓦生物科技有限公司 福州 350108

福州大学先进制造学院 食品营养与健康研究中心 福建晋江 362200

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茶渣 果胶 流变学性质 制膜潜力

2024

中国食品学报
中国食品科学技术学会

中国食品学报

CSTPCD北大核心EI
影响因子:1.079
ISSN:1009-7848
年,卷(期):2024.24(11)