首页|聚酰胺弹性体增韧聚乳酸改性研究

聚酰胺弹性体增韧聚乳酸改性研究

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选用聚酰胺弹性体(聚酰胺和聚氧乙烯的共聚物,PAE)与聚乳酸(PLA)熔融共混进行增韧改性。结果表明,当PAE弹性体含量在20%~30%(质量分数,下同)之间时,共混体系发生脆韧转变,最大冲击强度达到67.6J/m,但拉伸强度和模量大幅度下降;PAE弹性体含量为5%~10%时共混体系的拉伸强度保持率最高,而且断裂伸长率提高近40倍,综合性能较好;虽然扫描电子显微镜照片显示共混体系为两相分离,但是差示扫描量热分析数据均表明,随着PAE弹性体含量的增加,共混体系的玻璃化转变温度和熔点发生相应变化,证明该共混体系为半溶混性,即两相问存在一定的相互作用;热失重分析数据显示,PAE弹性体在一定程度上提高了PLA的热降解温度。
Study on Polyamide Elastomer Toughened Poly(lactic acid)
Polyamide dastomer(polyamide-polyoxyethylene copolymer, PAE) was used to toughen PLA via melt blending. It was found that a brittle-ductile transition occurred when PAE content was between 20 %-30 %. The maximum impact strength was 67.6 J/m, but the tensile strength and modulus decreased sharply. When the PAE contents were between 5 % -10 %, the blends exhibited the maximal comprehensive strength and toughness with the elongation at break increased by 40 times. SEM micropgraphs showed the blend was phase separated, but the DSC data showed that Tg and Tm changed as PAE content was changed. All the behavior indicated that the blend was partial miscibility for somewhat specific interaction between the two phases. TG data showed that the degradation temperature of PLA increased with increasing PAE content.

poly(lactic acid)polyamide elastomer toughening melt blending

张伟、魏发云

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南通大学纺织服装学院,江苏南通226019

东华大学材料科学与工程学院,上海201620

聚乳酸 聚酰胺弹性体 增韧 熔融共混

南通市生物技术和新医药计划项目

AS2011022

2012

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCDCSCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2012.(7)
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