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软质聚氯乙烯的热稳定体系研究

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研究了液体有机锡、固体有机锡、钙/锌(Ca/Zn)复合稳定剂、稀土稳定剂以及与辅助稳定剂水滑石(LDHs)复配对软质聚氯乙烯(PVC)热稳定性能、力学性能等性能的影响;采用热老化试验箱法、热失重法和转矩流变仪表征了材料的静态热稳定性和动态热稳定性.结果表明,固体有机锡具有良好的初期稳定性和透明性,Ca/Zn复合稳定剂的长 期稳定性和力学性能优异;Ca/Zn复合稳定剂与LDHs类混合使用后具有良好的协同效果,不仅提升了PVC的热稳定性,也提高了材料的力学性能及阻燃性能.
Study on Thermal Stability Systems in Soft Poly(vinyl chloride)
This paper reported an investigation on the complex effects of liquid/solid organ tin,Ca/ Zn composite,rare earth stabilizers and layered double hydroxides (LDHs) as an auxiliary stabilizer on the thermal stability and mechanical properties of soft poly(vinyl chloride)(PVC).Static and dynamic thermal stabilities were characterized by thermal aging test,thermogravimetric analysis and Haake torque rheometer.The results indicated that the use of solid organ tin could lead to a high initial stability and good transparency for soft PVC,whereas the Ca/Zn composite stabilizers made PVC a long-term stability and excellent mechanical properties.Combination of the Ca/Zn composite stabilizers and LDHs can not only improve the thermal stability of PVC,but also enhance its mechanical properties and flame retardancy.

poly(vinyl chloride)organ tincalcium/zinc composite thermal stabilizerthermal stability

王晓萌、蔺道雷、王原、武德珍

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北京化工大学化工资源有效利用国家重点实验室,北京100029

聚氯乙烯 有机锡 钙/锌复合稳定剂 热稳定性

国家重点研究计划(973计划)项目

2012CB720304

2017

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCDCSCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2017.31(9)
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