首页|PDMS/PVDF静电纺丝膜的制备及油水分离性能研究

PDMS/PVDF静电纺丝膜的制备及油水分离性能研究

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利用静电纺丝技术制备具有特殊浸润性表面用于油水分离研究。对比聚偏氟乙烯(PVDF)与聚二甲基硅氧烷(PDMS)不同配比下静电纺丝的成膜效果,并进行性能表征。研究表明,适量的PVDF可以对PDMS起到助纺与增塑的效果,且微球的存在使膜层表现出更好的疏水性。此外,膜层具有的对水高黏附性是受到毛细吸附与静电作用双重影响。当PVDF与PDMS的配比为2∶1时,膜层显示出对油包水乳液良好的选择透过性,水接触角可达150 °,油接触角几乎为0 °,油水分离率在98%以上,是油水分离材料良好的候选物。
Preparation and oil-water separation performance of PDMS/PVDF electrospun membranes
The PDMS/PVDF membranes with a special wetting surface were prepared for oil-water separation by using an electrospinning technology.The effect of mass ratio of PVDF to PDMS on the membrane-forming performance was investigated.The results indicated that an appropriate amount of PVDF could generate a spinning and plasticizing effect on PDMS,and the presence of microspheres resulted in better hydrophobicity for the membranes compared to those with-out microspheres.Furthermore,the membranes exhibited a high adhesion to water due to a capillary force and electro-static interactions.When the mass ratio of PVDF to PDMS was 2∶1,the membranes showed the optimal hydrophobicity with a water contact angle up to 150 ° and an oil contact angle closed to 0 °.The separation rate of the membranes for wa-ter-in-oil emulsions was more than 98%.This makes the membranes developed in this work a good candidate as an oil-water separation material.

electrospinningpolydimethylsiloxanepolyvinylidene difluorideoil-water separation

李杰、路祎祎、石文天、郭云杰、王宇科

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北京工商大学机械工程系,北京 100048

静电纺丝 聚二甲基硅氧烷 聚偏氟乙烯 油水分离

国家科技计划项目申报中心重点研发计划国家自然科学基金

2022YFC240600451975006

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(1)
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