首页|硅橡胶/多壁碳纳米管复合材料应变感知性能研究

硅橡胶/多壁碳纳米管复合材料应变感知性能研究

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通过开炼法制备出甲基乙烯基硅橡胶(VMQ)/多壁碳纳米管(MWCNT)复合材料,研究MWCNT含量对复合材料分散性能、导电性能及电阻-应变响应性能的影响.结果表明:适量的MWCNT能够均匀分散在VMQ中,形成三维隧穿导电网络,使复合材料具备较低的渗流阈值(2.51%,质量分数,下同),较大的传感范围(>200%)及高灵敏度(GF>2 546.16),在多次循环过程中具有稳定的电阻响应信号,特别是在4 000次循环中展现出优异的电阻信号稳定性,同时没有出现肩峰现象.通过隧道效应理论模型分析,解释了电阻-应变响应机理,明确复合材料具有对大变形隔震支座进行实时应变监测的潜力.
Strain-sensing properties of silicone rubber/multi-walled carbon nanotubes composites
In this study,a novel type of methyl vinyl silicone rubber(VMQ)/multi-walled carbon nanotubes(MWCNT)composites were prepared by using an open-mill method,and the effects of MWCNT content on the dispersion,electri-cal conductivity and resistance-strain response of the composites were studied.The results indicated that MWCNT could be uniformly dispersed in VMQ at a certain amount to form a three-dimensional tunneling conductive network.This en-sures the composites obtained a low percolation threshold of 2.51 wt%,a large sensing range higher than 200%,and a high sensitivity with a gauge factor higher than 2 546.16).The composites also present a stable resistance response signal in the process of multiple cycles,especially showing an excellent resistance signal stability without any shoulder peaks dur-ing 4 000 cycles.Through the theoretical model analysis of tunnel effect,the resistance-strain response mechanism was discussed.The composites exhibit the potential of real-time strain monitoring for large deformation isolation bearings.

multi-walled carbon nanotubesilicone rubberresistance-strain responsestructural health monitoringsmart sensing composite

万帮伟、杨洋

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昆明理工大学建筑工程学院,昆明 650000

云南省土木工程防灾重点实验室,昆明 650000

多壁碳纳米管 硅橡胶 电阻-应变响应 结构健康监测 智能传感材料

大宗固废规模化应用关键技术研发及工程示范

202202AG050020

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(2)
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