中国塑料2024,Vol.38Issue(2) :7-13.DOI:10.19491/j.issn.1001-9278.2024.02.002

树枝状聚合物对聚乳酸熔体微分电纺纤维膜的增韧改性研究

Study on toughening modification of poly(lactic acid)melt differential electrospun fiber membrane by dendrimer

谭晶 王智 王朔 付宏岩 李长金 李好义 杨卫民 张杨
中国塑料2024,Vol.38Issue(2) :7-13.DOI:10.19491/j.issn.1001-9278.2024.02.002

树枝状聚合物对聚乳酸熔体微分电纺纤维膜的增韧改性研究

Study on toughening modification of poly(lactic acid)melt differential electrospun fiber membrane by dendrimer

谭晶 1王智 1王朔 1付宏岩 1李长金 2李好义 1杨卫民 1张杨1
扫码查看

作者信息

  • 1. 北京化工大学机电工程学院,北京 100029
  • 2. 中国石化北京化工研究院,北京 100013
  • 折叠

摘要

采用树枝状聚合物CYD-T151为增塑剂,通过熔融共混方式对聚乳酸(PLA)进行改性,探究了CYD-T151含量、纺丝温度和纺丝电压对熔体微分电纺PLA及PLA/CYD-T151纤维平均直径、直径分布和纤维膜拉伸力学性能的影响.结果表明,树枝状聚合物CYD-T151的加入可有效提高PLA的熔体流动性,降低纤维细度,当CYD-T151含量(质量分数,下同)为1.25%、纺丝温度为240℃、纺丝电压为55 kV时,熔体电纺纤维的纤维平均直径为1.360 μm,较纯PLA减小了49.72%;树枝状聚合物CYD-T151作为增塑剂,可有效提高PLA熔体电纺纤维膜的韧性,当CYD-T151含量为1.25%,纺丝温度为240℃,纺丝电压为55 kV时,PLA/CYD-T151纤维膜的抗拉强度和断裂伸长率分别为11.50 MPa和92.33%,较纯PLA提高了4.07%和13.99%.

Abstract

Poly(lactic acid)(PLA)was modified through melt blending with dendritic polymer CYD-T151 as a plasticiz-er.The effects of CYD-T151 content,spinning temperature and spinning voltage on the mean diameter,diameter distri-bution and tensile mechanical properties of PLA/CYD-T151 fibers in melt differential electrospinning were investigated.The results indicated that the addition of dendritic polymer CYD-T151 effectively improved the melt fluidity and reduced the fiber fineness.When the content of CYD-T151 was 1.25%,the spinning temperature was 240℃,and the spinning voltage was 55 kV,the melt electrospinning fiber exhibited an average fiber diameter of 1.360 μm,which was 49.72%lower than that of pure PLA.Dendritic polymer CYD-T151 as a plasticizer could effectively improve the toughness of the PLA-based melt electrospinning fiber membrane.When the content of CYD-T151 was 1.25%,the spinning tem-perature was 240℃,and the spinning voltage was 55 kV.The PLA/CYD-T151 fiber membrane obtained tensile strength and elongation at break of 11.50 MPa and 92.33%,respectively,which were 4.07%and 13.99%higher than that of pure PLA.

关键词

树枝状聚合物/熔体微分电纺/聚乳酸纤维膜/纤维直径/拉伸力学性能

Key words

dendritic polymer/melt differential electrospinning/poly(lactic acid)fiber membrane/fiber diameter/tensile mechanical property

引用本文复制引用

基金项目

国家重点研发计划(2022YFB3804204)

中国石化总部科技部项目(222014)

出版年

2024
中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
参考文献量6
段落导航相关论文