首页|硅烷偶联剂改性蒙脱土/SBS/HVA高黏改性沥青最佳掺量确定及其性能评价

硅烷偶联剂改性蒙脱土/SBS/HVA高黏改性沥青最佳掺量确定及其性能评价

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通过(Box-Behnken)响应面法,以硅烷偶联剂改性过的蒙脱土、苯乙烯-丁二烯-苯乙烯(SBS)和高黏剂(HVA)各自的掺量作为影响因素,以沥青3大指标、170℃布氏黏度为评价标准建立模型,确定3种材料在沥青中的最佳掺量。结果表明,5%SBS、9%HVA和8%的改性蒙脱土复配高黏改性沥青性能最好,其针入度、延度、软化点、170℃布氏黏度分别为4。52 mm、42。9cm、86。1℃、2。371 Pa·s;相比于基质沥青和TPS高黏改性沥青,改性蒙脱土的加入大幅提高了沥青的高温性能与抗车辙能力,沥青黏度有着显著提升;振动峰的消失表明硅烷偶联剂对蒙脱土改性有化学反应。
Determination of optimum dosage of high-viscosity-modified asphalt based on silane-coupling-agent-modified montmorillonite/SBS/HVA blends and its performance
Using the Box-Behnken's response surface method and taking the dosages of silane-coupling-agent-modified montmorillonite,SBS,and high viscosity agent(HVA)as influence factors for asphalt,a model was established to de-termine the optimal dosages of three types of raw materials in the asphalt based on the Brinell viscosity at 170 ℃ as an evaluation criterion.The results indicated that the high-viscosity-modified asphalt containing 5 wt%SBS,9 wt%HVA,and 8 wt%modified montmorillonite exhibited the best performance,and its penetration,ductility,softening point,and Brinell's viscosity at 170 ℃ were determined to be 4.52 mm,42.9 cm,86.1 ℃,and 2.371 Pa·s,respectively.Dynamic shear and Brinell's viscosity tests show that,compared to the pristine asphalt and the high-viscosity-modified asphalt TPS,the addition of modified montmorillonite greatly improved the high-temperature performance and rutting resistance of asphalt,resulting in a significant improvement in the viscosity.The functional groups were analyzed by Fourier-trans-mission infrared spectroscopy.The disappearance of the vibration peaks indicated that the silane coupling agent involved a chemical reaction with montmorillonite in the modification process.

modified bitumenbox-behnkensilane coupling agentmodified montmorillonite

孙吉书、濮夏天、杨凯、靳灿章

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河北工业大学土木与交通学院,天津 300401

天津市政工程设计研究总院,天津 300051

改性沥青 响应面法 硅烷偶联剂 改性蒙脱土

天津市交通运输科技计划天津市自然科学基金

2022-1818JCTPJC54200

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(3)
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