首页|聚丙烯/氧化锆复合材料的制备及介电性能研究

聚丙烯/氧化锆复合材料的制备及介电性能研究

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通过乳液包覆法对氧化锆(ZrO2)粉末进行表面改性,以提高其在聚丙烯(PP)基体中的分散性,继而探究改性聚丙烯/氧化锆复合材料(PP/g-ZrO2)的介电性能、热学性能和力学性能。结果表明,1kHz测试频率下时,当g-ZrO2添加含量为50%时,PP/g-ZrO2的介电常数提高至4。28,介电损耗缓慢提升;此外,改性后复合材料在400 ℃时的热稳定性明显提高,当g-ZrO2添加量为20%时,复合材料拉伸强度可达38。33 MPa,结合改性前后ZrO2在PP基体中的团聚状态分析,当ZrO2填料添加量为30%时,复合材料的综合性能最优。
Preparation and dielectric properties of polypropylene/ZrO2 composite materials
The surface modification of zirconium oxide(ZrO2)powders was performed through emulsion coating to improve their dispersion in the polypropylene(PP)matrix.The dielectric,thermal,and mechanical properties of the modified ZrO2/PP(PP/g-ZrO2)composites were investigated.The results indicated that the dielectric constant of the PP/g-ZrO2 composites increased to 4.28,and their dielectric loss increased from 0.007 1 to 0.068 at a frequency of 1 kH at a ZrO2 con-tent of 50 wt%.In addition,the thermal stability of the PP/g-ZrO2 composites was significantly improved,and their ten-sile strength reached 38.33 MPa at a ZrO2 content of 20 wt%.Through analyzing the agglomeration state of ZrO2 in the PP matrix before and after modification,the composites achieved optimal overall performance at a ZrO2 content of 30 wt%.

zirconium oxidepolypropylenedielectric propertythermal stabilitycomposite

国江、许梦伊、李辉、黄想、林浩、姜胜宝、陈尚、陈程

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中国电力科学研究院有限公司,北京 100089

氧化锆 聚丙烯 介电性能 热稳定性 复合材料

国家电网总部科技项目

5500-202155350A-0-0-00

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(3)
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