首页|挤出吹塑工艺对PBAT/PLA共混体系微观结构与性能的影响

挤出吹塑工艺对PBAT/PLA共混体系微观结构与性能的影响

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通过调控工艺条件(机头温度、牵引速度)熔融共混挤出吹塑聚己二酸/对苯二甲酸丁二醇酯/聚乳酸(PBAT/PLA)原位成纤共混体系薄膜.结果表明,在较低的机头温度时,随着牵引速度的不断增加,分散相PLA在连续相PBAT中原位成纤,且微纤直径逐渐减小,结晶度先增大后下降.挤出吹塑薄膜的纵向拉伸强度和拉伸模量均先增加后减小.在机头温度为150℃、牵引速度为5.0 m/min时,共混体系中PLA成纤效果最明显;薄膜纵向拉伸强度达到40.0 MPa,比纯PBAT提高了20%;拉伸模量达到723.9 MPa,较纯PBAT提升明显.
Effect of extrusion blowing process on microstructure and properties of PBAT/PLA blend
The in-situ fibrillation films based on poly(adipic acid/butylene terephthalate)(PBAT)/poly(lactic acid)(PLA)blends were prepared by extrusion blowing through adjusting the extrusion process conditions such as die temper-ature and traction speed.The results indicated that PLA tended to form fibers in PBAT/PLA blend system with an in-crease in the traction speed at lower die temperature.The formed fibers tended to refine with an increase at first and then a decrease in the crystallinity.The longitudinal tensile strength and tensile modulus of in-situ fiber formed films also in-creased at first and then tended to decrease.The effect of PLA in-situ fibrillation was the most obvious in the blend at a die temperature of 150℃and a traction speed of 5.0 m/min.Meantime,the longitudinal tensile strength and modulus of the films reached 40.0 and 723.9 MPa,respectively.Their tensile strength was 20%higher than that of pure PBAT,whereas their tensile modulus was much higher than that of pure PBAT.

poly(adipic acid/butylene terephthalate)poly(lactic acid)in-situ fibrillationextrusion blow moldingtraction speeddie temperaturemicrostructurefilm

杨超永、郭金强、王富玉、张玉霞

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北京工商大学轻工科学与工程学院,北京 100048

聚己二酸/对苯二甲酸丁二醇酯 聚乳酸 原位成纤 挤出吹塑 牵引速度 机头温度 微观结构 薄膜

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(5)
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