首页|聚碳酸亚丙酯/乙酰化木质素抗紫外复合材料的制备与性能研究

聚碳酸亚丙酯/乙酰化木质素抗紫外复合材料的制备与性能研究

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为改善木质素(EL)与生物基聚碳酸亚丙酯(PPC)间的相容性,并赋予PPC抗紫外性,通过乙酰化反应制备得到了乙酰化木质素(ACEL),采用熔融共混法制备了PPC基复合材料。当ACEL的含量达到15%(质量分数,下同)时,复合材料的屈服强度从10 MPa提高至23 MPa,同时断裂伸长率达到725%。同时,ACEL的加入也赋予PPC优异的抗紫外老化性能,紫外光照射96 h后,PPC-ACEL-15复合材料的屈服强度和断裂伸长率的保持率均在80%以上,显著优于纯PPC和PPC-EL-15复合材料的屈服强度和断裂伸长率保持率。
Preparation and properties of UV-resistant poly(propylene carbonate)/acetylated lignin composites
To improve the compatibility between enzymatic lignin and bio-based poly(propylene carbonate)(PPC)and to endow PPC with UV resistance,acetylated lignin(ACEL)was prepared through an acetylation reaction and then was melt blended with PPC to obtain PPC-based composites.When 15 wt%(mass fraction,same below)ACEL was incor-porated,the composites showed an increase in the yield tensile properties from 10 to 23 MPa,and their elongation at break reached 725%.Meanwhile,the addition of ACEL also endows PPC with excellent UV resistance.After 96 h UV irradiation,the PPC-ACEL-15 composites showed retention rates of all above 80%in the yield strength and elonga-tion at break.These results are significantly better than those of pure PPC and PPC-EL-15 composites.

poly(propylene carbonate)ligninUV resistance

武莉、徐鹏武、杨伟军、马丕明

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江南大学化学与材料工程学院,江苏 无锡 214100

聚碳酸亚丙酯 木质素 抗紫外老化

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(7)
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