首页|纳米黏土与二氧化硅协同改性聚乳酸研究

纳米黏土与二氧化硅协同改性聚乳酸研究

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以聚乳酸(PLA)为树脂基体,研究不同含量纳米黏土与2 份SiO2协同填充,对PLA复合材料结构与性能的影响。结果表明,协同填充有效改善了PLA材料的结晶行为、熔体加工性、力学韧性和气体阻隔性能。当2份的SiO2和4份黏土杂化填充时,填料分散良好,获得的PLA复合材料展示了明显的韧性断裂和气体阻隔性能。相比没有填充PLA,拉伸断裂伸长率和冲击强度分别增加151%和74。1%,氧气和水蒸气透气系数分别下降67。4%和65。0%。过量黏土填充不利于材料韧性改善,对气体阻隔性能提高不明显。
Effect of hybrid reinforcement of nanoclay and silica on properties of poly(lactic acid)
PLA was adopted as a polymeric matrix to prepare PLA/nanoclay composites.The effect of the amount of nanoclay together with 2 phr SiO2 as a hybrid reinforcement on the structures and properties of the composites were inves-tigated.The results indicated that the crystallization behaviors,melt processability,mechanical toughness,and gas barri-er property of the PLA composites were significantly improved.The PLA composite with 2 phr SiO2 and 4 phr clay ex-hibited good filler dispersion,ductile fracture,and good gas barrier property.Compared to pure PLA,the PLA compos-ites presented an increase in elongation at break by 151%and in impact strength by 74.1%.Their oxygen and water va-por permeability coefficients were reduced by 67.4%and 65.0%,respectively.The excessive amount of clay was dis-advantageous to the toughness and also generated a slightly influence on gas barrier.

poly(lactic acid)hybrid reinforcementmechanical propertygas barrier property

王杰、辛德华、李晖、蒋洪石、周洪福、赵建国

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运城学院应用化学系,山西 运城,044000

北京工商大学化学与材料工程学院,北京,100048

煤基生态碳汇技术教育部工程研究中心,山西 大同,037009

聚乳酸 协同填充 力学性能 阻隔性能

煤基生态碳汇技术教育部工程研究中心开放基金石墨烯林业应用国家林业和草原局重点实验室开发基金运城市科技计划项目运城学院化学重点学科建设经费

YCKJ-2022045

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(7)
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