中国塑料2024,Vol.38Issue(9) :20-23.DOI:10.19491/j.issn.1001-9278.2024.09.004

MOF-74协同膨胀阻燃EVA及其性能研究

Performance of synergistic intumescent flame-retardant EVA with MOF-74

沈文涛 胡心蕊 张硕 许苗军
中国塑料2024,Vol.38Issue(9) :20-23.DOI:10.19491/j.issn.1001-9278.2024.09.004

MOF-74协同膨胀阻燃EVA及其性能研究

Performance of synergistic intumescent flame-retardant EVA with MOF-74

沈文涛 1胡心蕊 1张硕 1许苗军1
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作者信息

  • 1. 东北林业大学化学化工与资源利用学院,哈尔滨 150040
  • 折叠

摘要

将一种镍基金属有机框架材料(MOF-74)与焦磷酸哌嗪(PPAP)及三嗪成炭剂(CFA)以一定的质量比均匀混合后加入到乙烯-醋酸乙烯酯树脂(EVA)中,制备阻燃EVA材料并对其性能进行了表征.结果表明,PPAP/CFA(IFR)的质量比为3∶1,添加量为19%(质量分数,下同),材料在垂直燃烧测试时通过了UL 94 V-0级,极限氧指数(LOI)为26.9%;当IFR/MOF-74的质量比为97∶3,添加量为18%时,材料就能通过UL94V-0级,LOI值为27.1%;锥形量热测试表明,MOF-74的加入有效降低了材料的热量、烟气及一氧化碳的释放,表现了良好的协同阻燃作用,同时提高了阻燃剂与聚合物的相容性,使得阻燃EVA材料保持了良好的力学性能.

Abstract

A nickel-containing metal-organic framework material(MOF-74),piperazine pyrophosphate(PPAP),and a triazine charring foaming agent(CFA)were homogeneously mixed at a certain mass ratio and then incorporated into eth-ylene-vinyl-acetate resin(EVA).The performance of the resultant EVA composites was characterized.When 19 wt%PPAP/CFA(IFR)was introduced with a mass ratio of 3:1,the EVA composites obtain a UL 94 V-0 classification in the vertical burning tests as well as a limiting oxygen index(LOI)of 26.9%.IFR was mixed with MOF-74 at a mass ratio of 97:3,and then the resultant mixture was introduced into EVA,the resulting composites achieved a UL 94 V-0 classification along with an LOI of 27.1%at a IFR/MOF-74 loading of 18%.The cone calorimetry test results indicat-ed that the addition of MOF-74 effectively inhibited the release of heat,smoke and carbon monoxide during combustion.It was demonstrated that MOF-74 generated an excellent synergistic flame-retardant effect.Meanwhile,the compatibili-ty between the flame-retardant additives and polymer matrix was improved.Consequently,the mechanical properties of the resultant flame-retardant EVA composites were well maintained.

关键词

乙烯-醋酸乙烯酯/镍基金属有机框架材料/协同阻燃

Key words

ethylene vinyl acetate/nickel-containing metal-organic framework materials/synergistic flame retardant

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出版年

2024
中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCDCSCD北大核心
影响因子:0.574
ISSN:1001-9278
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