首页|高强电磁屏蔽环氧复合材料的3D打印工艺研究

高强电磁屏蔽环氧复合材料的3D打印工艺研究

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通过双喷头直书写3D打印工艺将高强纳米二氧化硅/环氧树脂(SiO2/EP)复合材料和高导电炭黑/环氧树脂(CB/EP)复合材料有序组装为三维交替排列的纳米二氧化硅/炭黑/环氧树脂(SiO2/CB/EP)复合材料.通过流变性能分析,添加11.6%(质量分数,下同)纳米二氧化硅和10%炭黑的环氧树脂具备优异的可打印性,并通过挤出压力和打印速度的调控实现了线宽为400 μm的线条稳定成型.结果表明,SiO2/CB/EP复合材料展现了优异的成型精度和规则有序的三维结构;所制备的SiO2/CB/EP复合材料的拉伸、压缩和弯曲强度分别为35、64、120 MPa,相较于SiO2/EP未出现严重衰减;同时,其电磁屏蔽效能最高可达25 dB,且主要以电磁波的吸收为屏蔽机制.
3D printing of epoxy-based composites with high strength and electromagnetic interference shielding ability
A dual-material 3D printing technique is developed to rationally construct nano-silica/carbon black/epoxy(SiO2/CB/EP)composites through alternately arranging nano-silica/epoxy(SiO2/EP)composites with high strength and car-bon black/epoxy(CB/EP)composites with high conductivity.According to the rheological properties,the epoxy com-posites with 11.6 wt.%SiO2 and 10 wt.%CB exhibits excellent printability.A stable diameter of 400 μm was achieved through controlling the extrusion pressure and printing speed.The SiO2/CB/EP composites show an excellent manufac-turing accuracy and a highly ordered 3D structure as verified by the optical and micro-CT images.The tensile,compres-sive and bending strengths of the SiO2/CB/EP composites were 35 MPa,64 MPa and 120 MPa,respectively,indicating that there is no attenuation compared to those of the SiO2/EP composites.Moreover,the electromagnetic interference shielding effectiveness of the composites is as high as 25 dB on the basis of the microwave absorbing mechanism.

epoxycompositethree-dimensional printingelectromagnetic interference shieldingmechanical property

曲道鹏、张涛、华晨曦、宋欣雨、程昌利、刘禹、王震宇

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江南大学机械工程学院,江苏无锡 214122

无锡市江大隔振器有限公司,江苏无锡 214024

江南大学江苏省食品先进制造装备技术重点实验室,江苏无锡 214122

环氧树脂 复合材料 三维打印 电磁屏蔽 力学性能

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(9)