首页|成核剂ST-NAB3改性扩链聚乳酸的微观结构与性能研究

成核剂ST-NAB3改性扩链聚乳酸的微观结构与性能研究

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使用转矩流变仪将扩链剂CEAX8840、成核剂ST-NAB3与PLA熔融共混制备改性PLA,采用扫描电子显微镜、偏光热台显微镜、差示扫描量热仪、热变形仪、万能试验机以及冲击测试仪对改性PLA微观结构、结晶性能以及力学性能和耐热性进行了表征与测试。结果表明,CEAX8840和ST-NAB3的含量分别为6%(质量分数,下同)和1%时,PLA的晶体最小,密度最大,结晶温度提高到123。9 ℃,结晶度达到44。9%;此外,其冲击强度和热变形温度分别提高到了 64。7 kJ/m2 和 84。9℃。
Study on microstructure and properties of ST-NAB3 nucleating agent-modified chain-extended poly lactic acid
PLA was melt-blended with a chain extender(CEAX8840)and a nucleating agent(ST-NAB3)by using a torque rheometer,and the microstructure,crystallization behavior,mechanical properties,and heat resistance of the modified PLA were characterized by suing scanning electron microscope,hot-plate polarizing microscope,differential scanning calorimeter,thermal deformation meter,universal testing machine,and impact tester.The results indicated that the modified PLA obtained the smallest crystal size at CEAX8840 and ST-NAB3 contents of 6 and 1 wt%,respec-tively;however,its crystal density was the highest.Moreover,the crystallization temperature and crystallinity degree of the modified PLA were increased to 123.9 ℃ and 44.9%,respectively.In addition,its impact strength and thermal de-formation temperature were increased to 64.7 kJ/m2 and 84.9 ℃,respectively.

poly(lactic acid)chain extendernucleating agentimpact strengththermal deformation temperature

丁馨怡、顿东星、秦骏熙、陈钰蕾、韩羽菲、张玉霞、周洪福

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北京工商大学轻工科学与工程学院,北京 100048

中国轻工业聚合物发泡材料加工与应用重点实验室,北京 100048

聚乳酸 扩链剂 成核剂 冲击强度 热变形温度

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(9)