首页|活化胶粉/纳米碳酸钙复合改性沥青性能影响及机理研究

活化胶粉/纳米碳酸钙复合改性沥青性能影响及机理研究

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目前日益增长的交通轴载量给沥青路面带来了更大的压力.本文选用不同活化程度的废旧胶粉(CR)和表面改性后的纳米碳酸钙(Nano-CaCO3)作为改性剂,制备活化胶粉/Nano-CaCO3复合改性沥青样品,并通过针入度、软化点、延度的比较提出了3种最优的改性体系.在此基础上,通过动态剪切流变仪(DSR)研究改性沥青的高温性能.通过薄膜烘箱试验(TFOT)研究改性沥青的抗老化性能.通过离析试验研究改性沥青的贮存稳定性.通过荧光显微镜(FM)和傅里叶变换红外光谱(FTIR)观测改性沥青的微观形貌和官能团变化.结果表明,活化处理可以改善胶粉与沥青的相容性,提高改性沥青的贮存稳定性.3种最优改性体系的改性沥青具有良好的高低温性能、抗老化性能、施工和易性和贮存稳定性.对于活化胶粉和活化胶粉/Nano-CaCO3复合改性沥青,改性过程中既发生物理反应,也发生化学反应.其中5#改性沥青为3种复合改性体系中综合性能最优的改性体系.
Study on properties and mechanism of asphalt modified with active rubber powder/nano-calcium carbonate composites
At present the increasing traffic axle load brings a greater pressure to asphalt pavement.In this study,the waste rubber powders with different activation degrees and the surface-modified nano-CaCO3 were employed as modifiers to pre-pare activated rubber powder/nano-CaCO3 composite-modified asphalts,and three optimal modification systems were pro-posed through comparing the penetration and softening point ductility of the modified asphalts.The high-temperature per-formance of the modified asphalts was investigated by DSR,their anti-aging performance was evaluated by a thin film oven test,their storage stability was assessed by a segregation test,and their morphology and functional groups were analyzed by fluorescence microscopy and Fourier-transform infrared spectroscopy.The results indicated that an activation treatment improved the compatibility between rubber powders and asphalt,thus enhancing the storage stability of the modified as-phalts.The modified asphalts obtained from the three optimal modification systems exhibited good high-and low-tempera-ture performance,anti-aging performance,workability,and storage stability.Both physical reaction and chemical reaction occurred in the modification of activated rubber powders and activated rubber powder/nano-CaCO3 composite-modified as-phalts.Among the three optimal modification systems,the sample 5#exhibited the best comprehensive performance.

rubber powdernano-CaCO3asphaltpropertymechanism

丁天雨、杨洋、晏永、张世博、赵艳芳

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昆明理工大学建筑工程学院,云南省土木工程防灾重点实验室,云南省绿色建造与智慧运维国际联合实验室,昆明 650500

胶粉 纳米碳酸钙 沥青 性能 机理

云南省科技厅重大科技专项计划

202202AG050020

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(10)