氟硅聚合物海洋防污涂料研究进展
Research progress in marine antifouling coatings based on fluorosilicone polymers
李曦 1王鑫 1齐文 1戚丁文2
作者信息
- 1. 广西民族大学化学化工学院,林产化学与工程国家民委重点实验室,广西林产化学与工程重点实验室/协同创新中心,南宁 530006
- 2. 辽宁省检验检测认证中心,沈阳 110032
- 折叠
摘要
海洋生物污损严重制约了海洋资源的开发利用,涂装海洋防污涂料是目前避免海洋生物污损最广泛、最有效、最经济的手段之一.氟硅聚合物海洋防污涂料是一类非常具有发展前景的污损脱附型涂料,本文介绍了氟硅聚合物的4种常见的合成方法,包含阴离子开环聚合法、原子转移自由基聚合法(ATRP)、硅氢加成反应法、硫醇-烯点击法,同时从有机链段改性和纳米材料改性两方面介绍了氟硅聚合物的改性研究进展,并指出了氟硅聚合物海洋防污涂料面临的挑战和未来发展方向.
Abstract
The severe pollution of marine organisms has greatly restricted the development and utilization of marine re-sources.At present the surface coating with marine anti-fouling coatings is one of the most widely used,effective,and economical methods to avoid marine organism pollution.The marine anti-fouling coatings based on fluorosilicone poly-mers are a class of non-stick coatings with great development prospects.This article introduced four common methods for synthesizing fluorosilicone polymers,including anionic ring-opening polymerization,atom transfer radical polymeriza-tion,hydrosilylation reaction,and thiol-ene click reaction.The research progress in the modification of fluorosilicone polymers was reviewed from the perspectives of organic chain segment modification and nanomaterial modification.Fur-thermore,the challenges and future development directions for the marine anti-fouling coatings based on fluorosilicone polymers were proposed.
关键词
氟硅聚合物/海洋防污涂料/聚氨酯/环氧树脂/丙烯酸系列化学品/纳米材料Key words
fluorosilicone polymer/marine antifouling coating/polyurethane/epoxide resin/acrylic series chemicals/nanometer material引用本文复制引用
基金项目
广西高等学校千名中青年骨干教师培育计划()
广西科技基地和人才专项(桂科AD20297016)
广西民族大学2019年引进人才科研启动项目(2019KJQD11)
辽宁省自然科学基金指导计划(2019-ZD-0848)
出版年
2024