首页|聚丙烯酸钠/桑黄菌段复合高吸水树脂的制备及溶胀性能研究

聚丙烯酸钠/桑黄菌段复合高吸水树脂的制备及溶胀性能研究

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采用微波辐射加热引发合成聚丙烯酸钠/桑黄菌段复合高吸水树脂(PISSR)。采用单因素试验研究变量配比方案,优化制备工艺,通过傅里叶变换红外光谱、热重分析仪、扫描电子显微镜及能谱对材料进行表征。结果表明,在桑黄菌段、引发剂、交联剂用量分别为丙烯酸的20%、0。60%、0。15%,丙烯酸中和度为85%、微波功率为500 W时,PISSR吸液倍率最大,在蒸馏水中为652。6g/g,0。9%NaCl溶液中为61。1 g/g;离子类型和电解质浓度是影响PISSR吸液性能的重要因素;PISSR表面粗糙多孔,富含Na、K、Ca元素,同时具有良好的保水性能以及再溶胀性能。
Preparation and swelling performance of sodium polyacrylate/Phellinus igniarius segment composite superabsorbent resin
A type of polyacrylic acid sodium/Phellinus igniarius section composite superabsorbent resin(PISSR)was syn-thesized through microwave irradiation.A single-factor experiment was conducted to investigate the variable ratio scheme and optimize the preparation processes.The as-synthesized materials were characterized by FTIR,TGA,SEM,and EDS.The results indicated that the neutralization degree of acrylic acid reached 85%when the dosage of Phellinus igniarius,initiator,and crosslinking agent was 20%,0.60%,and 0.15%of acrylic acid,respectively.PISSR presented the highest liquid absorption rates of 652.6 g/g in distilled water and 61.1 g/g in 0.9%NaCl solution at a microwave power of 500 W.Ion type and electrolyte concentration are two important factors affecting the liquid ab-sorption performance of PISSR.The surface of PISSR is rough,porous,and rich in Na,K and Ca elements,indicating good water retention and re-swelling performance.

Phellinus igniarius segmentsodium polyacrylatesuperabsorbent resinliquid absorption ratewater retention capacity

董志慧、曲楠、张雪、韩櫂濂、程志强

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吉林农业大学资源与环境学院,长春 130118

吉林省特色资源健康产品与医用材料科技创新中心,长春 130118

桑黄菌段 聚丙烯酸钠 高吸水树脂 吸液倍率 保水性能

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(12)