中国塑料2024,Vol.38Issue(12) :54-59.DOI:10.19491/j.issn.1001-9278.2024.12.009

柠檬酸改性苎麻纤维增强聚丁二酸丁二醇酯的性能研究

Study on performance of ramie fiber-reinforced polybutylene succinate through treatment with citric acid

孟承翰 罗皓文 刘昊 费继龙 杨健飞 杨振 贾良元
中国塑料2024,Vol.38Issue(12) :54-59.DOI:10.19491/j.issn.1001-9278.2024.12.009

柠檬酸改性苎麻纤维增强聚丁二酸丁二醇酯的性能研究

Study on performance of ramie fiber-reinforced polybutylene succinate through treatment with citric acid

孟承翰 1罗皓文 1刘昊 1费继龙 1杨健飞 1杨振 1贾良元1
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作者信息

  • 1. 合肥工业大学化学化工学院,合肥 230009
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摘要

采用柠檬酸(CA)对苎麻纤维(RF)进行改性制备苎麻纤维/聚丁二酸丁二醇酯(RF/PBS)生物复合材料.研究了CA处理后RF的热稳定性、结晶度和形貌的变化.讨论了CA处理对RF与PBS界面相互作用的机理.此外,制备了不同比例的CA-RF/PBS生物复合材料,根据其拉伸性能确定了 CA-RF/PBS生物复合材料中CA-RF的最佳质量分数配比为8%,其拉伸强度和拉伸模量分别为44.1、563.3 MPa.同时还将CA-RF/PBS与醋酸(AA)和氢氧化钠(SH)改性的RF/PBS的力学性能进行了比较.结果表明,AA-和SH-RF/PBS生物复合材料拉伸强度分别为40.2 MPa和41.0 MPa,均逊于CA-RF/PBS生物复合材料的力学性能.

Abstract

In this study,citric acid(CA)was used to modify ramie fiber(RF),and then the polybutadiene succinate(PBS)/modified RF bio-composites were prepared.Changes in the thermal stability,crystallinity,and morphology of CA-modified RF were investigated.The mechanism for the interface interaction between the CA-modified RF and PBS was analyzed.The optimal content of CA-modified RF for the bio-composites was determined to be 8 wt%according to their tensile properties.The bio-composites obtained tensile strength and modulus of 44.1 and 563.3 MPa,respective-ly.Meanwhile,the mechanical properties were compared between the PBS/CA-modified RF bio-composites and the corresponding bio-composites with the acetic acid(AA)-and sodium hydroxide(SH)-modified RF.The results indicat-ed that PBS/AA-and SH-modified RF bio-composites presented tensile strength of 40.2 MPa and 41.0 MPa,respec-tively,both of which were lower than those of the PBS/CA-modified RF bio-composites.

关键词

柠檬酸/苎麻纤维/聚丁二酸丁二醇酯/生物复合材料/力学性能

Key words

citric acid/ramie fiber/polybutylene succinate/bio-composite/mechanical property

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出版年

2024
中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
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